In this letter, the achievement of over 60 mW output power from pseudomorphic ultraviolet light-emitting diodes in continuous wave operation is reported. Die thinning and encapsulation improved the photon extraction efficiency to over 15%. Improved thermal management and a high characteristic temperature resulted in a low thermal rolloff up to 300 mA injection current with an output power of 67 mW, an external quantum efficiency (EQE) of 4.9%, and a wall plug efficiency (WPE) of 2.5% for a single-chip device emitting at 271 nm in continuous wave operation. # 2013 The Japan Society of Applied Physics M id-ultraviolet (MUV) light-emitting diodes (LEDs), which emit in the wavelength range of 250 to 275 nm, have demonstrated performance suitable for disinfection applications. [1][2][3][4][5] Their demonstrated advantages, such as small size, robustness, and instant turn-on have allowed them to replace mercury lamps in niche applications that do not require large power outputs. However, improvements in the output power and efficiency will enable the MUV LEDs to compete with mercury lamps in many more applications.The external quantum efficiency (EQE) is the product of the internal efficiency (IE) and the extraction efficiency, where the IE is defined as the ratio of the number of photons created per unit time to the current in the device divided by the electronic charge e, and the photon extraction efficiency is defined as the percent of created photons that are able to escape the chip. As previously reported, 1) it has been possible to produce pseudomorphic ultraviolet (PUV) LEDs on highquality AlN substrates where the low defect density in the pseudomorphic active layers is instrumental in achieving internal efficiencies near 70% which is comparable to values achieved in visible LEDs. However, the EQE of the PUVLEDs in the previous report was much lower than that of visible LEDs due to the low light extraction efficiency which was estimated to be less than 4%. Three main issues cause this low extraction efficiency. The first is absorption in the p-GaN contact layer, resulting in the inability to collect any photons directed downwards toward the p-contact in a flip-chipped device. The second is absorption in the AlN substrate. Although the 6.1 eV band gap of AlN suggests that it should be transparent to radiation with a wavelength longer than 205 nm, AlN substrates can have absorption in the mid-UV due to point defects. 6-9) For a typical substrate prepared at Crystal IS with a thickness of 200 m and an absorption coefficient of 35 cm À1 , approximately 50% of the light is absorbed prior to reaching the surface. Finally, the high refractive index contrast between AlN and air leads to a small critical angle for light extraction. Although visible LEDs are able to use high-refractive-index encapsulants to extract photons with angles greater than the critical angle, 10) these materials typically suffer from a low transparency and/or a low stability under mid-ultraviolet radiation.In the present paper, improvements in the...
This letter reports on the improved performance of a pseudomorphic ultraviolet light-emitting diode (LED). At 100 mA input current, 9.2 mW of quasi-CW output power was measured in a calibrated integrating sphere. The addition of a heat sink, required for CW and higher power operation, introduced a numerical aperture of 0.86, and 72 mW was measured in pulsed mode at 1.7 A, indicating that the total output power exceeds 100 mW when corrected by the coupling factor. The high characteristic temperature of 983 K was instrumental in achieving these record output powers for an LED with wavelength shorter than 265 nm. #
We report on the progress of high quality AlN bulk crystal growth by the sublimation‐recondensation technique and present a theoretical model for optimizing the growth conditions. The theoretical model is consistent with our experimental findings and projects a path to maximize the growth rate by adjusting the growth temperature, external nitrogen pressure and source‐to‐seed distance. The growth of large AlN boules has resulted in the demonstration of crack‐free AlN wafers up to 2‐inch diameter. The crystallinity of these AlN boules and wafers has been characterized by X‐ray techniques and etch pit density (EPD) measurements. The AlN wafers exhibited X‐ray rocking curves with a full width at half maximum (FWHM) close to 30 arcsec for both symmetric and asymmetric curves with a corresponding EPD of <104 cm–2. High quality homoepitaxial and graded AlGaN layers have been grown on these AlN substrates by organometallic vapor phase epitaxy (OMVPE). We have demonstrated pseudomorphic growth of graded Al1–x Gax N layers with a thickness of one order of magnitude higher than the expected critical thickness from the classical Matthews–Blakeslee theory. This achievement has resulted in low dislocation density AlGaN epi‐layers with both symmetric and asymmetric rocking curves routinely below 100 arcsec. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
High quality bulk aluminum nitride substrates were used to obtain pseudomorphic AlxGa1-xN layers with low dislocation density, smooth surfaces, and high conductivity. These layers were fabricated into mid-ultraviolet light emitting diodes with peak wavelengths in the range of 240–260 nm. The low dislocation density of the pseudomorphic quantum wells resulted in improved performance over previously published data. The output powers of the on-wafer measurements were greater than 5 mW in continuous wave operation, and 16 mW in pulsed operation. This was achieved utilizing single die (with an active area of 1×10-3 cm2).
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