A scheme that optimizes the converter of an ammonia synthesis plant to determine optimal inlet temperatures of the catalyst beds has been developed. The optimizer maximizes an objective function-The fractional conversion of nitrogen on the four catalyst beds of the converter subject to variation of the inlet temperature to each catalyst bed. An iterative procedure was used to update the initial values of inlet temperature thus ensuring accurate results and quick convergence. Converter model results obtained with optimized operating conditions showed significant increase in fractional conversion of 42.38% (from 0.1949 to 0.2586), increased rate of reaction evident in a 13.18% (0.5317 to 0.4616) and 23.84% (0.1946 to 0.1482) reduction in reactants (hydrogen and nitrogen) concentration respectively and a 56.48% increase (from 0.1181 to 0.1838) in ammonia concentration at the end of the fourth catalyst bed compared to results obtained with industrial operating conditions.
This paper presents profile of the physico-chemical properties of study areas of the research. Most frequently, in the Niger Delta zone spilled oil in the marine sediments is prevalent. The research paper therefore focused at first instance to evolve the parametric control properties which have direct interactions with the spilled oil. Samples sediments A, B, C, and D were collected from the designated study areas of Southern Ijaw, Ekeremor, Ogbia, Brass and Nembe local government areas hosting the major oil producing companies along the coastal regions of Niger Delta-Nigeria. The samples were subjected to instrumental analysis for determination of pH 5.2 (acidic); electrical conductivity 169 µS/cm; redox potential -134 mv; temperature 25.7 centigrade; bulk density 3.3; particle density 2.75; porosity 41.6; organic matter 8.60; clay 28.70; silt 56.80; sand 14.5; total hydrocarbon content 83.33; and the metallic components of the samples (mg/kg) stood as follows- Zinc (Zn) 1.47; Lead (Pb) 0.070; copper (Cu) 2.06; cadmium (0.51); Nickel (Ni) 0.82; manganese (Mn) 4.75; iron (Fe) 7.60; and chromium (Cr) 0.98. Table II showed sample Sediment A gave appreciable values on all the parameters for good judgment on the rest samples Sediment B, Sediment C and Sediment D results. The possible reasons being there are much physico-chemical interactions down the samples which bring concomitant effects on animals, fishes, humans’ health and regions degradation tendencies and perennial consequences of social agitations for remediation and compensations.
Models of an absorber for dehydration of natural gas using triethylene glycol are presented. The models were developed by applying the law of conservation of mass and energy to predict the variation of water content of gas and the temperature of the gas and liquid with time along the packing height. The models were integrated numerically using the finite divided difference scheme and incorporated into the MATLAB code. The results obtained agreed reasonably well with industrial plant data obtained from an SPDC TEG unit in Niger-Delta, Nigeria. Model prediction showed a percentage deviation of 8.65% for gas water content and 3.41% and 9.18% for exit temperature of gas and liquid, respectively.
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