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Abstract. Nucleation of atmospheric vapors produces more than half of global cloud condensation nuclei and so has an important influence on climate. Recent studies show that monoterpene (C10H16) oxidation yields highly-oxygenated products that can nucleate with or without sulfuric acid. Monoterpenes are emitted mainly by trees, frequently together with isoprene (C5H8), which has the highest global emission of all organic vapors. Previous studies have shown that isoprene suppresses new-particle formation from monoterpenes, but the cause of this suppression is under debate. Here, in experiments performed under atmospheric conditions in the CERN CLOUD chamber, we show that isoprene reduces the yield of highly-oxygenated dimers with 19 or 20 carbon atoms – which drive particle nucleation and early growth – while increasing the production of dimers with 14 or 15 carbon atoms. The dimers (termed C20 and C15, respectively) are produced by termination reactions between pairs of peroxy radicals (RO2·) arising from monoterpenes or isoprene. Compared with pure monoterpene conditions, isoprene reduces nucleation rates at 1.7 nm (depending on the isoprene/monoterpene ratio) and approximately halves particle growth rates between 1.3 and 3.2 nm. However, above 3.2 nm, C15 dimers contribute to secondary organic aerosol and the growth rates are unaffected by isoprene. We further show that increased hydroxyl radical (OH·) reduces particle formation in our chemical system rather than enhances it as previously proposed, since it increases isoprene derived RO2· radicals that reduce C20 formation. RO2· termination emerges as the critical step that determines the HOM distribution and the corresponding nucleation capability. Species that reduce the C20 yield, such as NO, HO2 and as we show isoprene, can thus effectively reduce biogenic nucleation and early growth. Therefore the formation rate of organic aerosol in a particular region of the atmosphere under study will vary according to the precise ambient conditions.

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The electrification of the automobile industry leads to an increasing demand for high-performance energy storage systems. The more complex the battery pack, the more complex the electronic components will become. Very high currents have to be transported in a short time and very fast electrical switching processes have to be made possible. These requirements have an effect on the required quality of the electrical connection. Furthermore, a joining process is required that offers short cycle times and a high degree of automation. Laser micro welding with fibre lasers (1070 nm) meets the requirements placed on joining technology. Due to the high beam quality, very small spot diameters and thus very high intensities can be achieved. Copper materials of high purity are used to achieve the high conductivity of the electrical connection. This material, in turn, poses a great challenge to the welding process, since the reflectance for the beam sources mentioned is above 95%.This paper presents a way of significantly reducing the reflectance for copper connectors and thus making the joining process more efficient. For this purpose, the copper connectors are first pre-processed with an ultrashort pulse laser process, which significantly increases the surface area. In a second step, bead-on-plate welds are carried out on the structured surfaces and the absorption coefficient is determined during the welding process with the aid of a double integrating sphere assembly in comparison to a bare copper sample.