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Optical characterization methods were applied to a series of microcrystalline silicon thin films and solar cells deposited by the very high frequency glow discharge technique. Bulk and surface light scattering effects were analyzed. A detailed theory for evaluation of the optical absorption coefficient ␣ from transmittance, reflectance and absorptance ͑with the help of constant photocurrent method͒ measurements in a broad spectral region is presented for the case of surface and bulk light scattering. The spectral dependence of ␣ is interpreted in terms of defect density, disorder, crystalline/amorphous fraction and material morphology. The enhanced light absorption in microcrystalline silicon films and solar cells is mainly due to a longer optical path as the result of an efficient diffuse light scattering at the textured film surface. This light scattering effect is a key characteristic of efficient thin-film-silicon solar cells.

Absorption losses at a nanorough silver back reflector of a solar cell were measured with high accuracy by photothermal deflection spectroscopy. Roughness was characterized by atomic force microscopy. The observed increase of absorption, compared to the smooth silver, was explained by the surface plasmon absorption. Two series of silver back reflectors ͑one covered with thin ZnO layer͒ were investigated and their absorption related to surface morphology.

We present an optical model for thin-film silicon solar cells (both single and multijunction) with nanorough surfaces/interfaces. For these cells, the optical absorptance within each layer and the total reflectance are computed taking into account roughness, angular distribution of scattered light, thicknesses, and optical constants of all layers. In the model, we combine coherent approach, scattering theory, and Monte Carlo tracing method. Results of the model are shown to be in good agreement with the experimentally measured spectral response and the total reflectance of solar cells. Some predictions of the ultimate solar cell performance based on the model are presented as well.

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The corrosion and passivation behaviour of molybdenum thin films obtained by Physical Vapor Deposition (PVD) was investigated in aerated chloride and sulfate solutions at different pH values. Open circuit potential (ocp) measurements, polarisation experiments and electrochemical impedance spectroscopy (EIS) were employed. The experimental results suggest that the metal surface is covered by a passive film; however, corrosion still occurs. For the samples assessed during the current research, the acidic electrolytes tended to be less corrosive; however, a limited passive region was associated with the most basic sulfate or chloride solution. The effect of the pH was found to be more pronounced than the effect of the ion (chloride or sulfate).

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