Dynamic spatial control of MOF position is obtained by incorporating carbon‐coated cobalt nanoparticles within metal organic framework (MOF)‐5 crystals. The cobalt framework composite obtained responds efficiently to magnetic stimuli. A luminescent functionality is added, showing that multifunctional MOF devices can be prepared. This new generation of adaptive material is tested as a position‐controlled molecular sensor.

The incorporation of highly luminescent core-shell quantum dots (QDs) within a metal-organic framework (MOF) is achieved through a one-pot method. Through appropriate surface functionalization, the QDs are solubilized within MOF-5 growth media. This permits the incorporation of the QDs within the evolving framework during the reaction. The resulting QD@MOF-5 composites are characterized using X-ray fluorescence, cross-sectional confocal microscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy, and small-angle X-ray scattering. The synergistic combination of luminescent QDs and the controlled porosity of MOF-5 in the QD@MOF-5 composites is harnessed within a prototype molecular sensor that can discriminate on the basis of molecular size.

The generation of single event transients generated by the impact of high-energy ions in high-speed photodetectors leads to bit error rate degradation in optical communications in radiation hard environments such as space. High-energy heavy ions, in particular, generate a submicron electron-hole pair plasma with a picosecond temporal profile that results in ultrahigh-injection carrier dynamics which induce large space-charge effects. These space-charge effects disturb the local electric field, thereby determining the peak and duration of a single event transient. In this paper, we examine the transient response of Si p-i-n photodetectors irradiated with focused single MeV heavy ions for a range of ion energies chosen to ensure the same end of range but different average plasma densities. We discuss the role of high-injection effects on the evolving spatiotemporal response with the aid of three-dimensional technology computer-aided design software. The result of both measurement and simulation points to charge collection being dominated by three clearly separable phases: (a) an ultrafast bandwidth-limited response which follows the excitation function, (b) an ambipolar diffusion-dominated expansion phase where space-charge screening limits the extracted current, and (c) a bipolar phase where the external field penetrates the electron-hole pair plasma resulting in rapid collection by drift.

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