The mobilized sediments expelled by the mud volcanoes in Trinidad correspond to liquefied argillaceous and sandy material in which the solid fraction is systematically polygenic and originating from several formations (Cretaceous to Pliocene). The mud is notably rich in thingrained quartz that is angular and frequently mechanically damaged related to shearing at great depth, during the sedimentary burial, and/or hydraulic fracturing processes. The exotic clasts are mostly fractured fragments from various formations of the tectonic wedge (mostly Palaeocene to Miocene). The origin of the solid particles of the mud is polygenic, including deep Cretaceous-Palaeogene horizons close to the décollement, and various materials from the stratigraphic pile pierced by the mud conduits. Moreover, the fluids expelled by the mud volcanoes have a deep origin and notably the gas phase is thermogenic methane generated probably below a depth of 5000 m. The effusions occur either during cycles of moderate effusion of mud and fluids (quiescence regime), or during catastrophic events responsible for the expulsion of huge volumes of mud, clasts and fluids (transient regime). Available subsurface data suggest that the deep structure of the mud volcanoes includes: (1) a focused deep conduit at depth in the zone of overpressure; (2) a mud chamber intruding the surrounding formations around and above the top of the abnormal pressure zone; and (3) a superficial outlet leading to the surface vents.
Geochemical characterizations of the Cretaceous formations at Site 603 are quite comparable with those at Site 105. In the Blake-Bahama and the Hatteras formations, the petroleum potential is medium (<5 kg HC/t of rock) to very low (<0.5 kg HC/t of rock), and the organic matter is mainly of type III origin, that is, terrestrial. At the top of the Hatteras Formation, there is a condensed series, which chiefly contains organic matter of type II origin, with up to 20 wt.% total organic carbon content in Core 603B-34 and 25 wt.% in Core 105-9. This accumulation corresponds to the Cenomanian/Turonian boundary event. An examination of dinoflagellates in the kerogen concentration assigns dates to the samples studied by organic geochemistry. The Cenomanian and Turonian age of the organic-matter-rich black claystones indicates a low rate of sedimentation, about 1 m/Ma. Furthermore, the occurrence of type II organic matter indicates an anoxic environment with insufficient oxygen renewal to oxidize the sinking hemipelagic organic matter. This organic enrichment is not related to local phenomena but to sedimentation over an extended area, because deposits are well known in various areas with different paleodepths in the North Atlantic.
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