Dr. James Petersen was killed during an armed robbery while doing research near Manaus, Brazil, on 13 Aug. 2005. Dr. Petersen was associate professor and chair of the Anthropology Department at University of Vermont. We will miss him as a valued colleague and good friend.

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[1] Black carbon (BC), the product of incomplete combustion of fossil fuels and biomass (called elemental carbon (EC) in atmospheric sciences), was quantified in 12 different materials by 17 laboratories from different disciplines, using seven different methods. The materials were divided into three classes: (1) potentially interfering materials, (2) laboratory-produced BC-rich materials, and (3) BC-containing environmental matrices (from soil, water, sediment, and atmosphere). This is the first comprehensive intercomparison of this type (multimethod, multilab, and multisample), focusing mainly on methods used for soil and sediment BC studies. Results for the potentially interfering materials (which by definition contained no fire-derived organic carbon) highlighted situations where individual methods may overestimate BC concentrations. Results for the BC-rich materials (one soot and two chars) showed that some of the methods identified

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A fractionation scheme that provided the measurement of a labile pool (particulate organic carbon), a charcoal-carbon pool, and a humic pool by difference was tested as a means of initialising the Rothamsted organic carbon turnover model version 26.3. Equating these 3 fractions with the resistant plant material, inert organic matter, and humic pools of the model, respectively, gave good agreement between measured and modelled data for 2 long-term rotation trials in Australia using a soil depth of 30 cm. At one location, Brigalow Research Station in Queensland, there were 3 distinct soil types, two clays and a duplex soil, in a semi-arid, subtropical climate. At this site, continuous wheat with some sorghum was established after clearing land under brigalow (Acacia harpophylla) and continued for 18 years. The second location was near Tarlee, South Australia, and was established on existing agricultural land. One soil type (red brown earth) with 2 rotations (continuous wheat and wheat–fallow) were available over a period of 8 years.The modelled and measured data were in good agreement for both locations but the level of agreement was substantially improved when the resistant plant material decomposition rate was reduced from 0.3 to 0.15/year. No other modifications were required and the resulting values provided excellent agreement between the modelled and measured data not only for the total soil organic carbon but also for the individual pools. Using this fractionation scheme therefore provides an excellent means of initialising and testing the Rothamsted model, not only in Australia, but also in countries with similar soil types and climate.For the first time, the work reported here demonstrates a methodology linking measured soil carbon pools with a conceptual soil carbon turnover model. This approach has the advantage of allowing the model to be initialised at any point in the landscape without the necessity for historical data or for using the model itself to generate an initial equilibrium pool structure. The correct prediction of the changing total soil organic carbon levels, as well as the pool structure over time, acts as an internal verification and gives confidence that the model is performing as intended.

This paper reviews current knowledge of soil organic carbon (SOC) dynamics with respect to physical protection, soil moisture and temperature, and recalcitrant carbon fractions (such as charcoal) in predominantly agricultural soils. These factors are discussed within the framework of current soil organic matter models. The importance of soil structure in the stabilisation of organic residues through physical protection has been documented previously in various studies. In addition, changes in soil structure associated with tillage can significantly affect soil organic matter decomposition rates. The concept of physical protection has been incorporated into several soil carbon models as a function of soil texture. While soil texture can affect the soil's capacity for aggregation and adsorption, factors such as soil moisture and temperature may further enhance or reduce the extent of physical protection. While adsorption and aggregation can slow decomposition processes, it is unlikely that these processes are solely responsible for the high mean residence times measured in biologically active surface soils. Accordingly, chemical recalcitrance appears to be the only mechanism by which soil organic carbon can be protected for long periods of time.

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Physical fractionation methods are based on the premise that soil organic matter (SOM) can be divided into pools of functional relevance. Physically uncomplexed organic matter (OM) is isolated on the basis of particle size and/or density. Our objective here is to review research on the biological and chemical characteristics of physically uncomplexed OM that demonstrates its value (or otherwise) as a meaningful pool of SOM. Chemical characterization indicates that fractions isolated by size are not identical to those separated by density; even materials separated using variations of a particular fractionation method (i.e., different sizes or different densities) have different chemical and biological properties. Physically uncomplexed OM often contains a substantial portion of whole soil carbon (C) and nitrogen (N) and, compared with the whole soil or heavy fraction, has a wide C/N ratio and high O‐alkyl (i.e., carbohydrates) and low carbonyl (i.e., proteins) C contents. The response of physically uncomplexed OM to changes in land use and management practices is greater than that of other labile OM fractions or the whole soil C and N. Studies to elucidate the nutrient availability of physically uncomplexed OM suggest that it is not an immediate source of nutrients. That the quantity of physically uncomplexed OM is not always related to the amount of plant residue inputs suggests that other factors may control its accumulation in soil. Thus the quantity and the biological and chemical properties of physically uncomplexed OM are affected by the amount, composition, and accessibility of plant residues entering the soil; environmental conditions that may enhance or constrain decomposition; and the fractionation technique used.