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Studies on the synthesis of esters of natural origin fatty acids (oleic acid) and a branched synthetic isostearic acid derived from oleic acid with commercially available selected higher polyols in the presence of homogeneous metallic catalysts have been carried out. The effects of the synthesis temperature, molar ratio and the catalysts amount have also been studied. It was shown that higher fatty acid conversion and selectivity to tri- and tetraesters were obtained for organotin catalyst Fascat 2003, which was used as the esterification catalyst. Anti-wear test confirmed good tribological properties of the obtained esters.

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A class of very important industrial-grade biolubricants was synthesized from plant-derived fatty acids (oleic and isostearic acid) by direct esterification of trimethylolpropane according to novel effective and high selective method using Sn bis(2-ethylhexanoate) as catalyst. Model transesterification reactions were performed with oleic and isostearic acids to optimize the reaction conditions to obtain maximum content of TMP triesters. Used specific homogeneous Sn catalyst allows to obtain TMP esters with very high content of triesters, above of 94 wt% without deep vacuum purifying distillation. Both TMP esters were evaluated for their physicochemical and tribological properties using ASTM standards. Both TMP esters exhibited high viscosity indexes and excellent low temperature properties.

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A study on the synthesis of esters of fatty acids of natural origin (oleic acid from rapeseed oil) and branched synthetic isostearic acid with commercially available alcohols C 8 -C 9 i.e. 2-ethylhexanol (2-EH) and 3,5,5-trimethylhexanol (TMH) in the presence of selected heterogeneous catalysts containing active sulfonic groups has been made. The catalysts were obtained using ready available amorphous silicas with different textural characteristics. The infl uence of catalyst porosity on the catalytic properties in the esterifi cation of fatty acids has been investigated. The effect of the synthesis temperature has also been studied. The results were compared with the results of esterifi cation with the use of acidic ion exchange resins. It was shown that catalysts obtained on the basis of amorphous silicas are good and reusable catalysts for the esterifi cation of fatty acids with higher alcohols.