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Recebido em 6/7/00; aceito em 15/1/01 COIODINATION OF ALKENES WITH OXYGENATED NUCLEOPHILES: INTRAMOLECULAR REACTIONS. A review on the electrophilic addition of iodine to alkenes in the presence of oxygen containing nucleophiles (cohalogenation reaction) is presented. The intermolecular reactions are discussed with emphasis in methods of reaction and synthetic applications of the resulting vicinal iodofunctionalized products (iodohydrins, β-iodoethers and β-iodocarboxylates).

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9‐anthraldehyde; 2‐ethoxy‐1‐naphthaldehyde product: 9‐Anthraldehyde reactant: 22.5 g. (0.13 mole) of anthracene product: 2‐Ethoxy‐1‐naphthaldehyde