Copper cadmium sulphide thin film was deposited onto glass (soda-lime) substrates using chemical bath deposition (CBD) technique at room temperature. Chemical, optical, structural, and microstructural features were examined via the Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), UV-Vis Spectroscopy, and High-resolution Transmission Electron Microscopy (HRTEM). FTIR revealed that the associated chemical bond was below the 900 cm-1 marks. The optical band-gap of 2.36 eV was estimated from the absorption analysis. X-ray diffraction measurements reveal that the deposited material is polycrystalline with hexagonal and cubic structures typical of the binary constituents of and thin films. The grain sizes were randomly distributed and ranged between 35 and 60 nm as indicated by the HRTEM.
Lead tin sulphide (Pb-Sn-S) thin films (TFs) were deposited on fluorine-doped tin oxide (FTO) substrates via the electrochemical deposition process using lead (II) nitrate [Pb(NO3)2], tin (II) chloride dehydrate [SnCl2.2H2O] and thiacetamide [C2H5NS] precursors as sources of lead (Pb), tin (Sn) and sulphur (S). The solution of all the compounds was harmonized with a stirrer (magnetic) at 300k. In this study, we reported on the improvements in the properties (structural and optical) of Pb-Sn-S TFs by varying the deposition time. We observed from X-ray diffractometer (XRD) that the prepared material is polycrystalline in nature. UV-Vis measurements were done for the optical characterizations and the band gap values were seen to be increasing from 1.52 to 1.54 eV with deposition time. In addition to this, the absorption coefficient and refractive index were also estimated and discussed.
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