Abstract:In the present work we report the use of regioregular poly(3-hexyltiophene) polymer (RR-P3HT) as a resistive sensor for the detection of chemical nerve agent simulant, dimethyl methylphosphonate (DMMP). The electrical response to DMMP vapour of RR-P3HT film deposited on ceramic (Al2O3) substrate in the room temperature was investigated. Results show that studied material is sensitive to DMMP trace amounts and selective against acetone and methanol. It also exhibits fast response and recovery times, repeatability and short-term stability.
In the present work, we report the use of regioregular poly(3-hexyltiophene) polymer (RR-P3HT) as a potential light-activated material for sensing the chemical nerve agent simulant dimethyl methylphosphonate (DMMP). The electrical response of thick films of RR-P3HT, deposited by spray-coating method onto a porous laminate substrate at room temperature, to DMMP vapours was investigated. The studied material was activated by light-emitting diodes that emitted light of different wavelengths. The sensing properties of RR-P3HT are considerably enhanced upon exposure to blue and yellow light. However, excitation by the low wavelength light (blue) caused degeneration of the material, resulting in lowered stability. In the case of the yellow light, degeneration was much slower and the limit of detection was 0.4 ppm. The studied material exhibited high selectivity, as it did not respond to 6 ppm of acetone and methanol vapours.
Here we present a summa~ of joint discussions on the results of three mountain experiments with large-scale emulsion chambers, at Pamir, Mt. Fuji and Chacahaya. Observations cover gamma quanta, hadrons and their clusters (called "families").The following topics are covered, concerning the characteristics of nuclear interactions the energy region 1014-1016 eV: (i) rapid dissipation seen in atmospheric diffusion of high-energy cosmic-rays; (i.i) multiplicity and Pt increase in produced pi-mesons in the fragmentation region; (iii) existence of large-P t jets, (iv) extremely hadron-rich family of the Ccntauro type: (v) exotic phenomena in the extremely high energy region beyond 1016 eV.
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