Naphthenic acids are toxic and corrosive substances in oil sands leachates comprising a group of saturated aliphatic and alicyclic carboxylic acids in hydrocarbon deposits (petroleum, oil sands bitumen, and crude oils). In the current study, photolysis was applied to naphthenic acid mixtures and individual compounds to determine the efficacy of a variety of UV/vis radiation sources for reducing both concentration and aryl hydrocarbon (Ah) receptor binding as a measure of toxicity. The results show that the concentrations of neither the compounds nor the mixtures were significantly reduced in Athabasca River water, although compositional changes occurred within the mixtures and Ah receptor binding potential was affected by photolysis. Photolysis at UV254 was the most effective radiation source applied in all instances.
Presence of a river in an urban setting may contribute positively to an aesthetically pleasing environment. Such aesthetic effects are not typically linked to specific economic activities and occur, for example, when residents are exposed to a river‐view. Qualities enhancing the aesthetic value of the river include the presence of parks, trails, and vegetation along the riverbanks. The value of aesthetic amenities provided by the South Saskatchewan to the City of Saskatoon residents was estimated in this study using non‐market methods. The implicit price of the river view was estimated using the Hedonic Price Model, whereas value through willingness to pay for property taxes or higher rents were also estimated using actual market data. The total annual value of the river to the City of Saskatoon through addition of aesthetic amenities was estimated at $1.2 million in 1989 dollars.
The photodegradation kinetics of atrazine (2-chloro-6-(ethylamino)-4-isopropylamino-1,3,5-triazine) and ametryne (2-methylthio-4-ethylamino-6-isopropylamino-s-triazine), in fresh and coastal salt water from Barbados, were measured under irradiation with artificial solar and UV254-radiation. The first-order rate constants were greater for ametryne than for atrazine, and the rates were reduced in seawater relative to fresh water, and in soil slurries relative to fresh water. However, rates were accelerated in the presence of iron(III) at pH 3 due to photo-Fenton type processes. This rate enhancement was reduced at ambient pH values (pH 7-7.5) representative of surface water in Barbados. These results have important implications for the relative persistence of these contaminants in aquatic environments in tropical areas.
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