PRECONCENTRATION BASED ON COPRECIPITATION USING SILVER CHROMATE AS A CARRIER FOR COPPER DETERMINATION BY FAAS. In the present paper, a preconcentration procedure based in the coprecipitation of copper by silver dichromate (Ag 2 CrO 4) and consecutive determination by flame atomic absorption spectrometry (FAAS) was proposed. The experimental factors were optimized from application of the Doehlert matrix and the conditions set: chromate concentration 5.8 × 10-4 mol L-1 , silver concentration 1.1 × 10-3 mol L-1 , pH 7.3 and disperser concentration HNO 3 0.38 mol L-1. Under these conditions, analytical parameters of the procedure were obtained, with the quantification limits of 0.76 μg L-1 , precision (based in the relative standard deviation, RSD %) with values lower than 2.7%, and preconcentration factor of 28. The accuracy of the procedure was given by addition/recovery test in water samples groundwater and mineral, and by comparison with results obtained by ICP-MS. The procedure developed presented be simple, sensitive and low cost, thus can be applied in the preconcentration and determination of copper in several water samples.
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