Globally, the amounts of metal ore deposits have been declining, so the research directions investigating the extraction of metals from materials that are classified as waste are gaining more importance every year. High concentrations of Cu, Pb, Zn, and Fe were analyzed in the sludge sediment (Zlaté Hory, Czech Republic), which is a waste product of the mining industry. In the bioleaching process, bacterial cells have been established as being able to convert metals from solid to liquid phase. However, the most important parameters of bioleaching are particle size, pH, and pulp density, thus our research focused on their optimization. The acidophilic and mesophilic bacteria Acidithiobacillus ferrooxidans were applied due to the high Fe content in the sample. The recovery of metals in the leachate was determined by F-AAS and the residual metal concentrations in the waste fraction were analyzed by XRF. The grain size fractions <40 µm –200 µm were investigated. The atomic absorption spectrometry (AAS) results show that the highest Fe (76.48%), Cu (82.01%), and Pb (88.90%) recoveries were obtained at particle size of 71–100 μm. Zn was dissolved for all fractions above 90%. Experiments with different pH values were performed at a pH of 1.6–2.0. The highest dissolution rates of Zn, Fe, and Cu were achieved with a suspension pH of 1.8, where 98.73% of Zn, 85.42% of Fe, and 96.44% of Cu were recovered. Due to the high percentage dissolution of metals, experiments were performed under pilot conditions in a bioreactor at a pulp density of 2.5% and 4.2% (w/v). From an economic point of view, the leaching time of 28 days was evaluated as sufficient.
In line with the requirements of the circular economy, the European Union’s waste management legislative changes also concern the treatment of sewage sludge. Although sewage sludge production cannot be prevented, its quantities may be reduced by the synergetic effect of energy recovery via choosing a proper technology. Sewage sludge is difficult to apply as fuel alone, because of its high moisture and ash content. However, its energy use will be increased by adding suitable waste materials (different types of plastics, waste tires and paper rejects). Most recently, the thermal utilization of sewage sludge via incineration or pyrolysis has grown in importance. This article describes the fuel parameters of particular waste materials and of their blends with sewage sludge in connection with laboratory-scale thermal decomposition in an inert atmosphere, for their potential use in a semi-pilot plant pyrolysis unit. For pyrolytic application, the results of thermogravimetric analysis are needed in order to know the maximal temperature of thermal decomposition in an inert atmosphere, maximal mass losses, and weight loss rates. The samples of different thermoplastics mixed with sewage sludge, and low-density polyethylene blends with sewage sludge, had the lowest residual masses (70–74%) and the highest weight loss rates (11–19%/min). On the other hand, the blend of polyester rejects from tire processing, paper rejects and sewage sludge had the second highest residual mass (60%) and the lowest weight loss rate (3%/min).
Coal reserved in Czech Republic are estimated to be 10 billion tones – bituminous coal about 37%, brown coal about 60% and lignite 3%. Bituminous coal is produced in Northern Moravia – in 2017 production of bituminous coal was 5.5 milion tons. Brown coal is mined in Nord-Wester Bohemia − production of brown coal in 2017 was 38.1 milion tons. Significant quantities of bituminous coal are exported to Slovakia, Austria, Germany and Hungary. In accordance with the National Energy Policy, coal will remain the main source of energy in the country in the future, despite the increased use of nuclear energy and natural gas. The government expects that in 2030 energy from coal will account for 30.5% of energy produced. There are five coal companies in the Czech Republic: OKD, a.s., the only bituminous coal producer and four brown coal mining companies: Severočeské doly a.s., owned by ČEZ, the largest producer of brown coal, Vršanská uhelná a.s., with coal resources until 2055, Severní energetická a.s. with the largest brown coal reserves in the Czech Republic and Sokolovska uhelná a.s., the smallest mining company extracting lignite. OKD operates coal in two mines Důlní závod 1 – (consists of three mines: ČSA Mine, Lazy Mine, Darkov Mine) and Mine Důlní závod 2 (two mines Sever, Jih). The article also presents a pro-ecological solution for the management of waste heaps after coal enrichment - a plant for the enrichment of coal waste from the Heřmanice heap.
The paper deals with a possible use of the bacterial detection system of SOS chromotest to test mutagenicity of waste dump water checking the mutagenicity degree on real samples from Praksice waste dump, which is a controlled waste dump with mixed industrial, municipal and inert wastes. The waste dump surface water samples were taken from a no-name influent stream springing below the waste dump body between 2005 and 2009. After metabolic activation by microsomal fraction in vitro, medium to high mutagenicity was registered in all the samples. The SOS chromotest is assessed as an effective and economically acceptable method to check and determine the mutagenicity degree of contaminated water.
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