a b s t r a c tSmall conjugated molecules are of great interest as promising alternatives to semiconducting polymers in organic photovoltaics (OPV). In this work, we introduce a more accurate assignment of the excited state of a promising squaraine (SQ) targeted for OPV application. From this assignment, we conclude that a mixed population of monomers and aggregates exists in spin-cast SQ:PC 61 BM bulk heterojunction (BHJ) films, where monomers indicate the presence of amorphous regions that could act as traps. Since crystallinity is critically important for efficient charge transport and exciton diffusion in the BHJ, we thermally anneal the as-cast films to reduce the amorphous regions. Our analysis of annealed films demonstrates a delicate trade-off between increased crystallinity and larger domain sizes. Crystallinity improves but often at the expense of larger crystal size, as supported by XRD and TEM study. Therefore, to achieve optimal OPV efficiency, we controlled the tradeoff to improve the crystallinity while maintaining a small, highly mixed BHJ morphology. We thus highlight the importance of chemical compatibility when designing small molecules for use in high efficiency BHJ devices. Significantly, we have connected theoretically validated spectroscopic assignment with the first full study of morphology and domain size control as they affect small molecule OPV active layers.
In this work, we have investigated a series of aniline-based squaraines, with varying solubilizing alkyl chains, as donor materials in bulk heterojunction (BHJ) solar cells. Although these squaraine molecules exhibit similar absorbance spectra and crystal structures, the difference in properties that drive the OPV performance becomes apparent when each squaraine is blended with PCBM. Thin film X-ray diffraction results demonstrate a disruption of squaraine crystallization in the presence of PCBM, more so for shorter side chain squaraines. As a result, the hole mobilities of BHJ films of shorter side chain squaraines show the largest drop when compared to their neat films, whereas the mobility decrease for the longer side chain counterparts is small. However, morphological studies have shown that the phase separation rapidly happens during the spin-casting process for longer side chain squaraines. Ultimately, it is the extent of phase separation that dominates the final device efficiency. Therefore, rational design can greatly be influenced as a result of our systematic materials properties overview for anilinic squaraines targeted for OPV.
The ternary polymerization strategy of incorporating different donor and acceptor units forming terpolymers as photovoltaic materials has been proven advantageous in improving power conversion efficiencies (PCEs) of polymer solar cells (PSCs). Herein, a series of low band gap nonconjugated terpolymer acceptors based on two different fused-ring electron-deficient building blocks (IDIC16 and ITIC) with adjustable photoelectric properties were developed. As the third component, ITIC building blocks with a larger π-conjugation structure, shorter solubilizing side chains, and red-shifted absorption spectrum were incorporated into an IDIC16-based nonconjugated copolymer acceptor PF1-TS4, which built up the terpolymers with two conjugated building blocks linked by flexible thioalkyl chain-thiophene segments. With the increasing ITIC content, terpolymers show gradually broadened absorption spectra and slightly down-shifted lowest unoccupied molecular orbital levels. The active layer based on terpolymer PF1-TS4-60 with a 60% ITIC unit presents more balanced hole and electron mobilities, higher photoluminescence quenching efficiency, and improved morphology compared to those based on PF1-TS4. In all-polymer solar cells (all-PSCs), PF1-TS4-60, matched with a wide band gap polymer donor PM6, achieved a similar open-circuit voltage ( V oc ) of 0.99 V, a dramatically increased short-circuit current density ( J sc ) of 15.30 mA cm –2 , and fill factor (FF) of 61.4% compared to PF1-TS4 ( V oc = 0.99 V, J sc = 11.21 mA cm –2 , and FF = 55.6%). As a result, the PF1-TS4-60-based all-PSCs achieved a PCE of 9.31%, which is ∼50% higher than the PF1-TS4-based ones (6.17%). The results demonstrate a promising approach to develop high-performance nonconjugated terpolymer acceptors for efficient all-PSCs by means of ternary polymerization using two different A–D–A-structured fused-ring electron-deficient building blocks.
To facilitate industrial applications, as well as for environmental and health purposes, there is a need to find less hazardous solvents for processing the photoactive layer of organic solar cells. As there are vast amounts of possibilities to combine organic solvents and solutes, it is of high importance to find paths to discriminate among the solution chemistry possibilities on a theoretical basis. Using Hansen solubility parameters (HSP) offers such a path. We report on some examples of solvent blends that have been found by modelling HSP for an electron donor polymer (TQ1) and an electron acceptor polymer (N2200) to match solvent blends of less hazardous solvents than those commonly used. After the theoretical screening procedure, solubility tests were performed to determine the HSP parameters relevant for the TQ1:N2200 pair in the calculated solvent blends. Finally, thin solid films were prepared by spin-coating from the solvent blends that turned out to be good solvents to the donor-acceptor pair. Our results show that the blend film morphology prepared in this way is similar to those obtained from chloroform solutions.
1-Chloronaphthalene (CN) has been a common solvent additive in both fullerene- and nonfullerene-based organic solar cells. In spite of this, its working mechanism is seldom investigated, in particular, during the drying process of bulk heterojunctions composed of a donor:acceptor mixture. In this work, the role of CN in all-polymer solar cells is investigated by in situ spectroscopies and ex situ characterization of blade-coated PBDB-T:PF5-Y5 blends. Our results suggest that the added CN promotes self-aggregation of polymer donor PBDB-T during the drying process of the blend film, resulting in enhanced crystallinity and hole mobility, which contribute to the increased fill factor and improved performance of PBDB-T:PF5-Y5 solar cells. Besides, the nonradiative energy loss of the corresponding device is also reduced by the addition of CN, corresponding to a slightly increased open-circuit voltage. Overall, our observations deepen our understanding of the drying dynamics, which may guide further development of all-polymer solar cells.
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