In the presence of sufficient tin(ll) chloride, chloro(trichlorostannato)platinum(ll) anions are rapidly absorbed by open-cell polyurethane foams from dilute hydrochloric acid solution. Sorptive capacities of up to 0.5 rnol kg-1 of Pt in foam may be obtained.
The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclopentadienyl rings undergoes an offset face-to-face π–π interaction [3.544 (6) Å] with the symmetry-related cyclopentadienyl ring of a neighbouring molecule.
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