Electrospun nanofibers are very popular in polymer nanocomposites because they have a high aspect ratio, a large surface area, and good mechanical properties, which gives them a broad range of uses. The application of nonwoven structures of electrospun nanofiber mats has historically been limited to enhancing the interlaminar responses of fiber-reinforced composites. However, the potential of oriented nanofibers to improve the characteristics of bulk matrices cannot be overstated. In this research, a multilayered laminate composite was created by introducing polyamide (PA6)-oriented nanofibers into an epoxy matrix in order to examine the effect of the nanofibers on the tensile and thermal characteristics of the nanocomposite. The specimens’ fracture surfaces were examined using scanning electron microscopy (SEM). Using differential scanning calorimetry (DSC) analysis, the thermal characteristics of the nanofiber-layered composites were investigated. The results demonstrated a 10.58% peak in the nanocomposites’ elastic modulus, which was compared to the numerical simulation and the analytical model. This work proposes a technique for the development of lightweight high-performance nanocomposites.
In this research, we focused on testing the physical and mechanical properties of the developed polyacrylonitrile (PAN) composite nanofibers with succinite (Baltic amber) and SiO2 particles using standard methods of nanofiber testing (physical and mechanical properties). Polyacrylonitrile composite nanofibers (based on the electrospinning method) were coated on an aluminum substrate for structural investigation. SEM was used to determine the average fiber diameter and standard deviation. The mechanical properties of the fibers were determined using a universal testing machine (NANO, MTS). We observed that constant or decreased levels of crystallinity in the ultrafine composite nanofibers led to the preservation of high levels of strain at failure and that the strength of nanofibers increased substantially as their diameter reduced. Improvements in PAN composite nanofibers with succinite and SiO2 nanopowder are feasible with continuous decreases in diameter. The drastically decreased strain at failure demonstrated a substantial reduction in viscosity (toughness) of the annealed nanofibers. Large stresses at failure in the as-spun nanofibers were a result of their low crystallinity. As a result, decreasing the diameter of PAN nanofibers from approximately 2 micrometers to 139 nanometers (the smallest nanofiber tested) resulted in instantaneous increases in the elastic modulus from 1 to 26 GPa, true strength from 100 to 1750 MPa, and toughness from 20 to 604 MPa.
The use of steel fiber reinforced concrete (SFRC) in structures with high physical-mechanical characteristics allows engineers to reduce the weight and costs of the structures, to simplify the technology of their production, to reduce or completely eliminate the manual labor needed for reinforcement, at the same time increasing reliability and durability. Commonly accepted technology is exploiting randomly distributed in the concrete volume fibers with random each fiber orientation. In structural members subjected to bending, major loads are bearing fibers located close to outer member surfaces. The majority of fibers are slightly loaded. The aim of the present research is to create an SFRC construction with non-homogeneously distributed fibers. We prepared layered SFRC prismatic specimens. Each layer had different amount of short fibers. Specimens were tested by four point bending till the rupture. Material fracture process was modelled based on the single fiber pull-out test results. Modelling results were compared with the experimental curves for beams. Predictions generated by the model were validated by 4PBT of 100 × 100 × 400 mm prisms. Investigation had shown higher load-bearing capacity of layered concrete plates comparing with plate having homogeneously distributed the same amount of fibers. This mechanism is strongly dependent on fiber concentration. A high amount of fibers is leading to new failure mechanisms—pull-out of FRC blocks and decrease of load-bearing capacity. Fracture surface analysis was realized for broken prisms with the goal to analyze fracture process and to improve accuracy of the elaborated model. The general conclusion with regard to modelling results is that the agreement with experimental data is good, numeric modelling results successfully align with the experimental data. Modelling has indicated the existence of additional failure processes besides simple fiber pull-out, which could be expected when fiber concentration exceeds the critical value.
In many structural applications, concretes reinforced with short metal or synthetic fibers (fiber-reinforced concrete (FRC)) have a number of advantages over traditional concretes reinforced with steel rebars reinforcement, such as easier and more economical production, wear resistance, impact resistance, integrity, etc. In the present study, several concrete mixes were developed and prismatic FRC specimens were fabricated. Their structural behaviors were studied using bending tests until prisms were fractured. Two types of fibers, namely, steel and polypropylene (PP) and three different concrete matrixes were investigated, testing in total 12 FRC prismatic specimens. Every group of FRC had the same concrete matrix, but different internal fiber architecture. All specimens were tested by Four-Point Bending (4PBT). The analysis was carried out with a goal to determine the workability and flexural tensile strength of all FRC groups, comparing these parameters with fracture modelling results. Single crack formation and opening model were established. Crack is crossing whole stretched part of the prism’s orthogonal crossection. Crack is opening, fibers are bridging the crack and are pulling out. Load bearing curves in the model were compared with experimentally obtained.
# Corresponding author Communicated by Ivars KnçtsPolyamide fibre containing amber particles was fabricated. The amber particles were obtained by grinding technology using planetary ball-mills. Scanning electron microscopy and granulometry testing were used to characterise the structure and the size of prepared amber particles. Fourier transform infrared spectroscopy was used to analyse the chemical structure of the amber particles. The amber particles were characterised with average size up to 3 µm. The chemical composition of amber before and after the grinding remained unchanged. The amber particles were melt-extruded using polyamide 6 as the matrix. Melt spinning processing was used to fabricate polyamide-amber filaments. Pre-oriented yarns and fully drawn yarns were obtained after hotdrawing experiments. Reported experimental findings of amber composite fibre could be important for textile applications.
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