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Layered hexagonal boron nitride (h-BN) thin film is a dielectric that surpasses carrier mobility by reducing charge scattering with silicon oxide in diverse electronics formed with graphene and transition metal dichalcogenides. However, the h-BN effect on electron doping concentration and Schottky barrier is little known. Here, we report that use of h-BN thin film as a substrate for monolayer MoS can induce ∼6.5 × 10 cm electron doping at room temperature which was determined using theoretical flat band model and interface trap density. The saturated excess electron concentration of MoS on h-BN was found to be ∼5 × 10 cm at high temperature and was significantly reduced at low temperature. Further, the inserted h-BN enables us to reduce the Coulombic charge scattering in MoS/h-BN and lower the effective Schottky barrier height by a factor of 3, which gives rise to four times enhanced the field-effect carrier mobility and an emergence of metal-insulator transition at a much lower charge density of ∼1.0 × 10 cm (T = 25 K). The reduced effective Schottky barrier height in MoS/h-BN is attributed to the decreased effective work function of MoS arisen from h-BN induced n-doping and the reduced effective metal work function due to dipole moments originated from fixed charges in SiO.

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For transition metal dichalcogenides, the fluctuation of the channel current due to charged impurities is attributed to a large surface area and a thickness of a few nanometers. To investigate current variance at the interface of transistors, we obtain the low-frequency (LF) noise features of MoTe2 multilayer field-effect transistors with different dielectric environments. The LF noise properties are analyzed using the combined carrier mobility and carrier number fluctuation model which is additionally parametrized with an interfacial Coulomb-scattering parameter (α) that varies as a function of the accumulated carrier density (Nacc) and the location of the active channel layer of MoTe2. Our model shows good agreement with the current power spectral density (PSD) of MoTe2 devices from a low to high current range and indicates that the parameter α exhibits a stronger dependence on Nacc with an exponent -γ of -1.18 to approximately -1.64 for MoTe2 devices, compared with -0.5 for Si devices. The raised Coulomb scattering of the carriers, particularly for a low-current regime, is considered to be caused by the unique traits of layered semiconductors such as interlayer coupling and the charge distribution strongly affected by the device structure under a gate bias, which completely change the charge screening effect in MoTe2 multilayer. Comprehensive static and LF noise analyses of MoTe2 devices with our combined model reveal that a chemical-vapor deposited h-BN monolayer underneath MoTe2 channel and the Al2O3 passivation layer have a dissimilar contribution to the reduction of current fluctuation. The three-fold enhanced carrier mobility due to the h-BN is from the weakened carrier scattering at the gate dielectric interface and the additional 30% increase in carrier mobility by Al2O3 passivation is due to the reduced interface traps.

As the thickness becomes thinner, the importance of Coulomb scattering in two-dimensional layered materials increases because of the close proximity between channel and interfacial layer and the reduced screening effects. The Coulomb scattering in the channel is usually obscured mainly by the Schottky barrier at the contact in the noise measurements. Here, we report low-temperature (T) noise measurements to understand the Coulomb scattering mechanism in the MoS channel in the presence of h-BN buffer layer on the silicon dioxide (SiO) insulating layer. One essential measure in the noise analysis is the Coulomb scattering parameter (α) which is different for channel materials and electron excess doping concentrations. This was extracted exclusively from a 4-probe method by eliminating the Schottky contact effect. We found that the presence of h-BN on SiO provides the suppression of α twice, the reduction of interfacial traps density by 100 times, and the lowered Schottky barrier noise by 50 times compared to those on SiO at T = 25 K. These improvements enable us to successfully identify the main noise source in the channel, which is the trapping-detrapping process at gate dielectrics rather than the charged impurities localized at the channel, as confirmed by fitting the noise features to the carrier number and correlated mobility fluctuation model. Further, the reduction in contact noise at low temperature in our system is attributed to inhomogeneous distributed Schottky barrier height distribution in the metal-MoS contact region.

In this study, Ce 0.65 Zr 0.25 RE 0.1 O 2−δ (RE = Tb, Gd, Eu, Sm, Nd, Pr, and La) solid solutions were successfully prepared by the glycine-nitrate process and tested for CO oxidation activity. The X-ray diffraction results confirmed the formation of complete Ce 0.65 Zr 0.25 RE 0.1 O 2−δ solid solutions. The Raman spectroscopy measurements suggested the presence of oxygen vacancies due to defective structure formation and further evidenced the formation of solid solution. The high-resolution transmission electron microscopy observations showed the nanocrystalline nature of the solid solutions. From X-ray photoelectron spectroscopy analysis it was revealed that the cerium, terbium, and praseodymium are present in +3 and +4 oxidation states. The UV−vis diffuse reflectance spectroscopy indicated that the Pr 3+ ions in the Ce 0.65 Zr 0.25 Pr 0.1 O 2−δ system provoked a significant increase in the Ce 3+ fraction on the surface. H 2 temperature-programmed reduction measurements showed an enhanced surface reduction at much lower temperatures for Ce 0.65 Zr 0.25 Pr 0.1 O 2−δ sample compared to others, indicating increased oxygen mobility in these samples, which enable the enhanced oxygen diffusion at lower temperatures. Significantly high CO oxidation activity is exhibited by Ce 0.65 Zr 0.25 Pr 0.1 O 2 solid solution.