We describe the one-pot synthesis, unique geometries and intriguing host–guest properties of a new class of supramolecular macrocycles – biphen[n]arenes (n = 3, 4).
We present a new investigation of the intergalactic medium near reionization using dark gaps in the Lyβ forest. With its lower optical depth, Lyβ offers a potentially more sensitive probe to any remaining neutral gas compared to the commonly used Lyα line. We identify dark gaps in the Lyβ forest using spectra of 42 QSOs at z
em > 5.5, including new data from the XQR-30 VLT Large Programme. Approximately 40% of these QSO spectra exhibit dark gaps longer than 10 h
−1 Mpc at z ≃ 5.8. By comparing the results to predictions from simulations, we find that the data are broadly consistent both with models where fluctuations in the Lyα forest are caused solely by ionizing ultraviolet background fluctuations and with models that include large neutral hydrogen patches at z < 6 due to a late end to reionization. Of particular interest is a very long (L = 28 h
−1 Mpc) and dark (τ
eff ≳ 6) gap persisting down to z ≃ 5.5 in the Lyβ forest of the z = 5.85 QSO PSO J025−11. This gap may support late reionization models with a volume-weighted average neutral hydrogen fraction of 〈x
H I〉 ≳ 5% by z = 5.6. Finally, we infer constraints on 〈x
H I〉 over 5.5 ≲ z ≲ 6.0 based on the observed Lyβ dark gap length distribution and a conservative relationship between gap length and neutral fraction derived from simulations. We find 〈x
H I〉 ≤ 0.05, 0.17, and 0.29 at z ≃ 5.55, 5.75, and 5.95, respectively. These constraints are consistent with models where reionization ends significantly later than z = 6.
The selective binding behavior of a series of nitrile derivatives by ethylated pillar[6]arene (EtP6A) is described. This work represents the first example of complexation of neutral guests by pillar[6]arenes, although those for pillar[5]arenes have been well documented.
Room-temperature polariton lasing is achieved in GaN microrods grown by metal-organic vapor phase epitaxy. We demonstrate a large Rabi splitting (Ω = 2g0) up to 162 meV, exceeding the results from both the state-of-the-art nitride-based planar microcavities and previously reported GaN microrods. An ultra-low threshold of 1.8 kW/cm2 is observed by power-dependent photoluminescence spectra, with the linewidth down to 1.31 meV and the blue shift up to 17.8 meV. This large Rabi splitting distinguishes our coherent light emission from a conventional photon lasing, which strongly supports the preparation of coherent light sources in integrated optical circuits and the study of exciting phenomena in macroscopic quantum states.
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