The grain boundary
in copper-based electrocatalysts has been demonstrated
to improve the selectivity of solar-driven electrochemical CO2 reduction toward multicarbon products. However, the approach
to form grain boundaries in copper is still limited. This paper describes
a controllable grain growth of copper electrodeposition via poly(vinylpyrrolidone)
used as an additive. A grain-boundary-rich metallic copper could be
obtained to convert CO2 into ethylene and ethanol with
a high selectivity of 70% over a wide potential range. In situ attenuated
total reflection surface-enhanced infrared absorption spectroscopy
unveils that the existence of grain boundaries enhances the adsorption
of the key intermediate (*CO) on the copper surface to boost the further
CO2 reduction. When coupling with a commercially available
Si solar cell, the device achieves a remarkable solar-to-C2-products
conversion efficiency of 3.88% at a large current density of 52 mA·cm–2. This low-cost and efficient device is promising
for large-scale application of solar-driven CO2 reduction.
A novel carbon nanotubes reinforced polyurethane sponge with superhydrophobic, superoleophilic and high mechanical properties shows potential for applications in oil–water separation.
Tuning the facet exposure of Cu could promote the multi-carbon (C2+) products formation in electrocatalytic CO2 reduction. Here we report the design and realization of a dynamic deposition-etch-bombardment method for Cu(100) facets control without using capping agents and polymer binders. The synthesized Cu(100)-rich films lead to a high Faradaic efficiency of 86.5% and a full-cell electricity conversion efficiency of 36.5% towards C2+ products in a flow cell. By further scaling up the electrode into a 25 cm2 membrane electrode assembly system, the overall current can ramp up to 12 A while achieving a single-pass yield of 13.2% for C2+ products. An insight into the influence of Cu facets exposure on intermediates is provided by in situ spectroscopic methods supported by theoretical calculations. The collected information will enable the precise design of CO2 reduction reactions to obtain desired products, a step towards future industrial CO2 refineries.
:Polysulfone microcapsules containing tung oil were synthesized by a solvent evaporation method. The mean diameter and wall thickness of the synthesized microcapsules were approximately 130 μm and 9 μm, respectively. High thermal stability of the microcapsules with a thermal degradation onset temperature of 350°C was obtained. The multi-functional coating was fabricated by incorporating the microcapsules containing tung oil into an epoxy matrix. The self-healing and self-lubricating functions were evaluated by corrosion and tribology test. 10 wt% microcapsules embedded in epoxy coating offered optimum results. The microcapsules showed excellent anticorrosion performance in scratched coatings, which was attributed to the formation of a cross-linked polymer film after tung oil was released from the damaged microcapsules. The frictional coefficient and wear rate of the self-lubricating coating decreased significantly as compared to the neat epoxy. The formation of a transfer film from releasing tung oil and the entrapment of wear particles in the cavities left by the ruptured microcapsules were the major antifriction mechanism.
A series of novel green lubricants with dissolved lignin in [Choline][Amino Acid] ([CH][AA]) ionic liquids (ILs) have been synthesized in this work. The effect of lignin on the thermal and tribological properties of the lignin/[CH][AA] lubricants were systematically investigated by means of thermogravimetric analysis, differential scanning calorimetry, and friction and wear tester. The lignin in [CH][AA] has been demonstrated effective additive to improve thermal stability, reduce wear rate and stabilize friction coefficient of lignin/[CH][AA] lubricants. Density function theory calculation on the electronic structure of [CH][AA] ILs reveals the atomic natural charge of ILs and their hydrogen bonding capability with lignin. Moreover, these green lubricants show excellent anti-corrosive property against commercial aluminum and iron boards. The strong physical adsorption of [CH][AA] ILs onto steel surface and the reciprocal hydrogen bonding between [CH][AA] ILs and lignin synergistically contribute to the enhanced lubrication film strength and thus the tribological property of these new lubricants. This work provides a new perspective on utilizing complete bio-products in advanced tribological lubrication systems. In addition, this will open a new application venue of lignin to improve product value in lignocellulosic biomass utilization.
Multifunctional coatings are in urgent demand in emerging fields. In this work, nanocomposite coatings with extraordinary self-cleaning, antiwear, and anticorrosion properties were prepared on aluminum substrate by a facile spraying technique. Core-shell structured polyaniline/functionalized carbon nanotubes (PANI/fCNTs) composite and nanosized silica were synergistically integrated into ethylene tetrafluoroethylene (ETFE) matrix to construct lotus-leaf-like structures, and 1H,1H,2H,2H- perfluorooctyltriethoxysilane (POTS) was used to decrease the surface energy. The composite coating with 6 wt % PANI/fCNTs possesses superamphiphobic property, with contact angles of 167°, 163°, and 159° toward water, glycerol, and ethylene glycol, respectively. This coating demonstrates stable nonwetting performance over a wide temperature range (<400 °C), as well as outstanding self-cleaning ability to prevent contamination by sludge, concentrated H2SO4, and ethylene glycol. Superamphiphobic surface property could be maintained even after 45 000 times abrasion or bending test for 30 times. The coating displayed strong adhesive ability (grade 1 according to the GB/T9286) on the etched aluminum plate. The superamphiphobic surface could be retained after immersion in 1 mol/L HCl and 3.5 wt % NaCl solutions for 60 and 90 d, respectively. It should be noted that this coating reveals significantly improved anticorrosion performance as compared to the bare ETFE coating and ETFE composite coating without PANI/fCNTs. Such coatings with integrated functionalities offer promising self-cleaning and anticorrosion applications under erosive/abrasive environment.
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