Figure 6. Dual-ion SPEs with specific design. a) SPE prepared by vertically aligned 2D sheets and its microstructure. Reproduced with permission. [92] Copyright 2019, Wiley. b) Illustration of sandwich-type composite electrolyte (SCE) combined "ceramic-in-polymer" (CIP) electrolyte and "polymer-inceramic"(PIC) electrolyte. Reproduced with permission.
A three-electrode system composed of TiO 2 /Ni as the working electrode, porous nickel as the counter electrode, and saturated calomel electrode (SCE) as the reference electrode was used for the photoelectrocatalytic degradation of organic compounds. The photoelectrocatalytic degradation of sulfosalicylic acid (SSal) under anodic bias potential was investigated. It is shown that SSal can be degraded effectively as the external potential is increased up to 700 mV (vs SCE). The characteristics by electrochemical impedance spectroscopy (EIS) of the photoelectrocatalytic degradation of sulfosalicylic acid (SSal) was also investigated. It is shown from the EIS that the photoelectrocatalytic degradation appears to be a simple reaction on the electrode surface, suggesting that only one step of charge transfer is involved in the electrode process. The value of the resistance of charge transfer for the photoelectrocatalytic reaction of SSal manifests itself not only in the reaction rate, but also in the separation efficiency of the photogenerated electron-hole pairs. The separation efficiency of the electron-hole pairs under N 2 atmosphere is higher than that under O 2 atmosphere.
Stretchable electrodes are playing important roles in the measurement of bio‐electrical signals especially in wearable electronic devices. These electrodes usually adopt commercial elastomers such as polydimethylsiloxane or polystyrene‐ethylene‐butylene‐styrene as substrates, which result in poor stability and reliability due to weak interfacial adhesion between electrodes and human skin. Here, dopamine is introduced into the hydrogen bonding based elastomer as pendent groups. The elastomer shows both mechanical strength and adhesion strength at the same time. It exhibits high stress at break (1.9 MPa) and high fracture strain (5100%). Significantly, it exhibits a high adhesive strength (≈62 kPa) and underwater adhesive strength (≈16 kPa) with epithelial tissue. Thus, a stretchable bio‐interfacial electrode is fabricated by spray‐coating silver nanowires on the elastic substrate, which is stretchable, self‐healable, and highly adhesive and suitable for electromyogram measurement.
We aim to understand the scale-dependent evolution of uranium bioreduction during a field experiment at a former uranium mill site near Rifle, Colorado. Acetate was injected to stimulate Fe-reducing bacteria (FeRB) and to immobilize aqueous U(VI) to insoluble U(IV). Bicarbonate was coinjected in half of the domain to mobilize sorbed U(VI). We used reactive transport modeling to integrate hydraulic and geochemical data and to quantify rates at the grid block (0.25 m) and experimental field scale (tens of meters). Although local rates varied by orders of magnitude in conjunction with biostimulation fronts propagating downstream, field-scale rates were dominated by those orders of magnitude higher rates at a few selected hot spots where Fe(III), U(VI), and FeRB were at their maxima in the vicinity of the injection wells. At particular locations, the hot moments with maximum rates negatively corresponded to their distance from the injection wells. Although bicarbonate injection enhanced local rates near the injection wells by a maximum of 39.4%, its effect at the field scale was limited to a maximum of 10.0%. We propose a rate-versus-measurement-length relationship (log R' = -0.63 log L - 2.20, with R' in μmol/mg cell protein/day and L in meters) for orders-of-magnitude estimation of uranium bioreduction rates across scales.
Hierarchical porous materials especially the silica-based ones are undergoing rapid development due to potential applications in the fields of catalysis, adsorption, separation, and biomedical processes.Although various synthesis methods involving emulsions, colloids, and surfactants have been reported, synthesis of hierarchical porous silicas (HPS) with complex mesophase transformations by using a fourcomponent microemulsion (surfactant/cosurfactant/oil/water) templating approach is still challenging.Herein, we have successfully synthesized porous silica materials by introducing n-butanol (Bu) as the cosurfactant and 1,3,5-trimethylbenzene (TMB) as the oil component in a four-component P123-nbutanol-1,3,5-trimethylbenzene-water system. By simply increasing the molar ratio of Bu to TMB continuously while keeping a fixed mass of TMB in the mean time, mesophase transformations, progressing from mesocellular foam (MCF) via a vesicle-like structure to an ordered 2D hexagonal structure (SBA-15), can be observed. Moreover, an opposite phase transformation process was also proved by gradually increasing the molar ratio of TMB to Bu by maintaining a certain value for the Bu content in the initial system. All the mixed phase silica materials including hexagonal-vesicle, MCFvesicle-hexagonal, and MCF-disordered-SBA-15-type show hierarchically porous structures. The mechanism for the mesophase transformation was proposed and a micelle/microemulsion method with bimodal templates was put forward to form hierarchical porous silicas with a mixed phase of the MCFdisordered-SBA-15-type structure. Furthermore, a series of Al-containing mesoporous silicas with different structures (hexagonal, vesicle, MCF, MCF-vesicle-hexagonal, and MCF-disordered-SBA-15type) were used as catalyst supports for dibenzothiophene hydrodesulfurization. The NiMo/Alhierarchical porous silica catalyst with pore structures of MCF-disordered-SBA-15-type displayed the best hydrodesulfurization performance among all the studied catalysts.
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