Elucidating the effects of crystallization‐induced blue‐shift emission of a newly synthesized di‐boron complex (DBC) by enhanced photoluminescence (PL) and electrochemiluminescence (ECL) in the annihilation pathway was realized for the first time. The 57 nm blue‐shift and great enhancement in the crystalline lattice relative to the DBC solution were attributed to the restriction of intramolecular rotation (RIR) and confirmed by PL imaging, X‐ray diffraction, as well as DFT calculations. It was discovered that ECL at crystalline film/solution interfaces can be further enhanced by means of both co‐reactant route and RIR. The RIR contributions with co‐reactant increased ECL up to 5 times more. Very interestingly, the co‐reactant system was found to give off a red‐shifted light emission. Mechanistic studies reveal that a difference between location of the ECL in the co‐reactant route and that in the annihilation pathway leads to an alternative emission wavelength.

CO 2 -switchable desiccants have been prepared and evaluated for the drying of isobutanol. CO 2 addition triggered the binding of water to the drying agent, while CO 2 displacement triggered the water's facile release. The switchable desiccants were capable of absorbing more water and were able to 10 regenerate at much milder conditions than traditional desiccants like molecular sieves.

The effect of beta-cyclodextrin (beta-CD) on the improvement of the fungicidal activity of iprodione has been investigated. The inclusion complexation of beta-CD with iprodione has been prepared and characterized by integrating some analytical techniques (such as electrospray ionization-mass spectrometry, differential scanning calorimetry, thermogravimetry, x-ray diffraction, and scanning electron microscopy) and molecular simulation methods. The beta-CD/iprodione inclusion complex has exhibited different spectroscopic features and properties from iprodione. The stoichiometric ratio and stability constant describing the extent of formation of inclusion complexes have been determined by phase solubility studies. The calculated apparent stability constant of the iprodione/beta-CD complex was 407.5 M-1. The obtained inclusion complexes were found to significantly improve the water solubility of iprodione, and there is a 4.7-fold increase in the presence of 13 mM beta-CD as compared with the solubility of iprodione in deionized water in the absence of beta-CD. The bioassay demonstrated that the complex displayed over two-fold increase of the fungicidal activity. In addition, the possible structure of the beta-CD/iprodione complex was proposed according to the results of the molecular dynamic simulation. The present study provided useful information for a more rational application of iprodione, diminishing the use of organic solvents and increasing its efficacy.

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With vigorous development of the maritime trade, many intelligent algorithms have been proposed to avoid collisions due to resulting casualties and increased costs. According to the international regulations for preventing collisions at sea (COLREGs) and the self-evolution ability of the intelligent algorithm, the collision avoidance trajectory can be more consistent with the requirements of reality and maritime personnel. In this paper, the optimization of ship collision avoidance strategies is realized by both an improved multiobjective optimization algorithm NSGA-II and the ship domain under the condition of a wide sea area without any external disturbances. By balancing the safety and economy of ship collision avoidance, the avoidance angle and the time to the action point are used as the variables encoded by the algorithm, and the fuzzy ship domain is used to calculate the collision avoidance risk to achieve collision avoidance. The simulation results show that the proposed method can optimize the ship collision avoidance strategy and provide a reasonable scheme for ship navigation.

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