Since 2006, we have conducted a geological exploration of the Khammuane area in southeastern Laos. Several thick sequences of potash deposits containing sylvite and carnallite were discovered from drilling Paleocene strata of the Thangon Formation (E 1 tg).To constrain the origin of the brine that formed thick sequences of salt mineral deposits, we measured the strontium and boron isotope composition of some salt minerals in the potash deposit. Boron isotope composition of halite-and potash-associated minerals in the Khammuane potash deposit varied from 19.91% to 31.01‰, which differs significantly from continental evaporates (-6.83‰ --5.79‰) but is very close to that of salts precipitated from evapo-concentrated seawater (10‰-36‰). The 87 Sr/ 86 Sr ratios (0.707542 to 0.709461) of salts were also close to the values of Paleocene seawater (0.70772 to 0.707830). The content of Br -(0.01%-0.25%) and Br×10 3 /Cl ratios (0.10-0.52) of halite were >10 times higher than that of common continental salts. These characteristics indicate clearly that the Laos potash deposits were deposited from seawater. The small variation in boron and strontium isotopes in all salt sedimentary sequences (gypsum-halite-potash-halite) also suggests that the recharge source should be stable and the effects of other continental water mixing are negligible. Large-scale potash deposits are commonly precipitated from seawater. Hence, the results of recent regional drilling work and geochemical research suggest extensive potash resources could occur in the Thangon Formation of southeastern Laos. potash deposit, strontium isotope, boron isotope, marine origin, Laos
Citation:Tan H B, Ma H Z, Li B K, et al. Strontium and boron isotopic constraint on the marine origin of the Khammuane potash deposits in southeastern Laos.
Material sources of the northern deserts and the Loess Plateau in China are always one of the critical focuses in Quaternary and paleoclimate fields. In this paper, the method of Sr-Nd isotope geochemistry is applied to explore the relationship in material source between the Erdos desert and Chinese Loess Plateau. The ε Nd (0) value of the <75 µm silicate fraction between -11.8 and -17.2 is more positive in the west than in the east, and its 87 Sr/ 86 Sr ratio varies from 0.719218 to 0.714824 without similar characteristics in the Erdos desert. In addition, there are Sr-Nd isotopic differences between different grain-size fractions of eolian sand in the Erdos desert. The coarse-grained fractions mainly originated from local parent rock weathering, but the fine-grained fractions were probably affected by the input of foreign materials. Geographical distribution of Sr-Nd isotopes (especially Nd isotopes) of <75 µm silicate fractions indicates that the input of foreign materials into the Erdos desert decreases gradually from its west to east. The ε Nd (0) (0) values of eolian silicate fractions in the western-central Loess Plateau mostly fall in a very narrow range of -9~-11.5, suggesting a uniform source region. However, there is a large Sr isotope variation resulting from different pretreating methods employed by researchers. The ε Nd (0) and 87 Sr/ 86 Sr values of eolian silicate fractions in the eastern Loess Plateau both change markedly. The differences in Sr-Nd isotopes of eolian silicate fractions between the eastern and western-central Loess Plateau indicate that there are different sources for eolian silicate materials in the two sub-areas. Sr-Nd isotopes, especially Nd isotopes of the <75 µm silicate fractions in the Erdos desert are clearly different from those of eolian silicate fractions in the western-central part, but roughly close to those of eolian silicate fractions in the eastern part of the Chinese Loess Plateau, which shows that the Erdos desert was perhaps a main source for the eastern Loess Plateau but not for the western-central Loess Plateau.
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