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Novel di-μ-oxo dimanganese(IV) complexes, [MnIV(N-R-sal)2(μ-O)]2, with bidentate Schiff base ligands, N-alkyl-salicylideneamine, N-R-salH (R = n-C3H7 (Pr), n-C4H9 (Bu), n-C6H13 (Hx), n-C8H17 (Oct), n-C12H25 (Dod), or n-C18H37 (Octd)), have been prepared and characterized by spectroscopies, magnetic susceptibilities, thermal analysis and X-ray crystallography.

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Novel di-μ-oxo dimanganese(IV) complexes with Schiff base ligands, N,N′-disalicylidene-1,2-diaminobenzene, salophenH2 and N,N′-disalicylidene-1,4-diaminobutane, salbnH2, [MnIV(salophen)(μ-O)]2 and [MnIV(salbn)(μ-O)]2 have been prepared and characterized by spectroscopies, magnetic susceptibilities and X-ray crystallography.