P-Chirogenic phosphine/sulfide hybrid ligands 1 were prepared by the use of optically active phosphine-boranes as the intermediates. The palladium complexes of the ligands exhibited high catalytic activity and enantioselectivity in allylic alkylation of 1-acetoxy-1,3-diphenylprop-2-ene with malonate esters.
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ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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