Recently, non-fullerene n-type organic semiconductors have attracted significant attention as acceptors in organic photovoltaics (OPVs) due to their great potential to realize high-power conversion efficiencies. The rational design of the central fused ring unit of these acceptor molecules is crucial to maximize device performance. Here, we report a new class of non-fullerene acceptor, Y6, that employs a ladder-type electron-deficient-core-based central fused ring (dithienothiophen[3.2-b]-pyrrolobenzothiadiazole) with a benzothiadiazole (BT) core to fine-tune its absorption and electron affinity. OPVs made from Y6 in conventional and inverted architectures each exhibited a high efficiency of 15.7%, measured in two separate labs. Inverted device structures were certified at Enli Tech Laboratory demonstrated an efficiency of 14.9%. We further observed that the Y6-based devices maintain a high efficiency of 13.6% with an active layer thickness of 300 nm. The electron-deficient-core-based fused ring reported in this work opens a new door in the molecular design of high-performance acceptors for OPVs.
Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved.
This article provides an overview on the recent development of solution processed organic, inorganic, and hybrid interfacial materials for bulk-heterojunction polymer solar cells. The introduction of proper interfacial materials to optimize the electronic and electrical properties between the interfaces of the light-harvesting active layer and the charge-collecting electrode has become an important criterion to improve the performance of polymer solar cells. The electronic processes at these interfaces play a critical role in determining the efficiency for photon-to-electricity conversion. An ideal interface requires the formation of Ohmic contact with minimum resistance and high charge selectivity to prevent charge carriers from reaching the opposite electrodes. For long-term stability of polymer solar cells, interfaces with matched surface energy are required to prevent interfacial dewetting and delamination. Several classes of interfacial materials including inorganic metal oxides, crosslinkable charge-transporting materials, conjugated polymer electrolytes, self-assembled functional molecules, and graphene-based materials are highlighted and the integration of these interfacial materials with new low bandgap polymers and fullerene derivatives as active materials in different device architectures is also discussed.
The field of organic electronics has been developed vastly in the past two decades due to its promise for low cost, lightweight, mechanical flexibility, versatility of chemical design and synthesis, and ease of processing. The performance and lifetime of these devices, such as organic light‐emitting diodes (OLEDs), photovoltaics (OPVs), and field‐effect transistors (OFETs), are critically dependent on the properties of both active materials and their interfaces. Interfacial properties can be controlled ranging from simple wettability or adhesion between different materials to direct modifications of the electronic structure of the materials. In this Feature Article, the strategies of utilizing surfactant‐modified cathodes, hole‐transporting buffer layers, and self‐assembled monolayer (SAM)‐modified anodes are highlighted. In addition to enabling the production of high‐efficiency OLEDs, control of interfaces in both conventional and inverted polymer solar cells is shown to enhance their efficiency and stability; and the tailoring of source–drain electrode–semiconductor interfaces, dielectric–semiconductor interfaces, and ultrathin dielectrics is shown to allow for high‐performance OFETs.
In biological complexes, cascade structures promote the spatial separation of photogenerated electrons and holes, preventing their recombination. In contrast, the photogenerated excitons in organic photovoltaic cells are dissociated at a single donor-acceptor heterojunction formed within a de-mixed blend of the donor and acceptor semiconductors. The nanoscale morphology and high charge densities give a high rate of electron-hole encounters, which should in principle result in the formation of spin-triplet excitons, as in organic light-emitting diodes. Although organic photovoltaic cells would have poor quantum efficiencies if every encounter led to recombination, state-of-the-art examples nevertheless demonstrate near-unity quantum efficiency. Here we show that this suppression of recombination arises through the interplay between spin, energetics and delocalization of electronic excitations in organic semiconductors. We use time-resolved spectroscopy to study a series of model high-efficiency polymer-fullerene systems in which the lowest-energy molecular triplet exciton (T1) for the polymer is lower in energy than the intermolecular charge transfer state. We observe the formation of T1 states following bimolecular recombination, indicating that encounters of spin-uncorrelated electrons and holes generate charge transfer states with both spin-singlet ((1)CT) and spin-triplet ((3)CT) characters. We show that the formation of triplet excitons can be the main loss mechanism in organic photovoltaic cells. But we also find that, even when energetically favoured, the relaxation of (3)CT states to T1 states can be strongly suppressed by wavefunction delocalization, allowing for the dissociation of (3)CT states back to free charges, thereby reducing recombination and enhancing device performance. Our results point towards new design rules both for photoconversion systems, enabling the suppression of electron-hole recombination, and for organic light-emitting diodes, avoiding the formation of triplet excitons and enhancing fluorescence efficiency.
The performance and stability of unencapsulated inverted bulk-heterojunction solar cells with zinc oxide (ZnO) made by different processes as the electron selective contact are compared to conventional bulk-heterojunction solar cells. The low temperature processed inverted devices using ZnO nanoparticles on indium tin oxide plastic substrates showed high power conversion efficiency of ∼3.3%. This inverted device structure possessed much better stability under ambient conditions retaining over 80% of its original conversion efficiency after 40days while the conventional one showed negligible photovoltaic activity after 4days. This is due to the improved stability at the poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/Ag interface.
A plethora of solution-processed materials have been developed for solar cell applications. Hybrid solar cells based on light absorbing semiconducting polymers infiltrated into mesoporous TiO2 are an interesting concept, but generating charge at the polymer-metal oxide heterojunction is challenging. Metal-organic perovskite absorbers have recently shown remarkable efficiencies but currently lack the range of color tunability of organics. Here, we have combined a fullerene self-assembled monolayer (C60SAM) functionalized mesoporous titania, a perovskite absorber (CH3NH3PbI3-xClx), and a light absorbing polymer hole-conductor, P3HT, to realize a 6.7% efficient hybrid solar cell. We find that photoexcitations in both the perovskite and the polymer undergo very efficient electron transfer to the C60SAM. The C60SAM acts as an electron acceptor but inhibits further electron transfer into the TiO2 mesostructure due to energy level misalignment and poor electronic coupling. Thermalized electrons from the C60SAM are then transported through the perovskite phase. This strategy allows a reduction of energy loss, while still employing a "mesoporous electron acceptor", representing an exciting and versatile route forward for hybrid photovoltaics incorporating light-absorbing polymers. Finally, we show that we can use the C60SAM functionalization of mesoporous TiO2 to achieve an 11.7% perovskite-sensitized solar cell using Spiro-OMeTAD as a transparent hole transporter.
With the demonstration of small-area, single-junction polymer solar cells (PSCs) with power conversion efficiencies (PCEs) over the 10% performance milestone, the manufacturing of high-performance large-area PSC modules is becoming the most critical issue for commercial applications. However, materials and processes that are optimized for fabricating small-area devices may not be applicable for the production of high-performance large-area PSC modules. One of the challenges is to develop new conductive interfacial materials that can be easily processed with a wide range of thicknesses without significantly affecting the performance of the PSCs. Toward this goal, we report two novel naphthalene diimide-based, self-doped, n-type water/alcohol-soluble conjugated polymers (WSCPs) that can be processed with a broad thickness range of 5 to 100 nm as efficient electron transporting layers (ETLs) for high-performance PSCs. Space charge limited current and electron spin resonance spectroscopy studies confirm that the presence of amine or ammonium bromide groups on the side chains of the WSCP can n-dope PC71BM at the bulk heterojunction (BHJ)/ETL interface, which improves the electron extraction properties at the cathode. In addition, both amino functional groups can induce self-doping to the WSCPs, although by different doping mechanisms, which leads to highly conductive ETLs with reduced ohmic loss for electron transport and extraction. Ultimately, PSCs based on the self-doped WSCP ETLs exhibit significantly improved device performance, yielding PCEs as high as 9.7% and 10.11% for PTB7-Th/PC71BM and PffBT4T-2OD/PC71BM systems, respectively. More importantly, with PffBT4T-2OD/PC71BM BHJ as an active layer, a prominent PCE of over 8% was achieved even when a thick ETL of 100 nm was used. To the best of our knowledge, this is the highest efficiency demonstrated for PSCs with a thick interlayer and light-harvesting layer, which are important criteria for eventually making organic photovoltaic modules based on roll-to-roll coating processes.
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