Abstract-This paper investigated comparatively the characteristics of four types of artificial magnetic conductor (AMC) surface, including a mushroom-like (electromagnetic band gap) EBG, uniplanar compact EBG (UC-EBG), Peano curve, and Hilbert curve, as a ground plane for a low-profile antenna. The AMC surface structures are designed to have an in-phase reflection property for a plane wave of normal incidence in the vicinity of 2.45 GHz. The bandwidths of the in-phase reflection for the AMC surfaces and return losses, radiation patterns, and gains of the horizontal wire antennas on the AMC ground planes are all measured and compared with each other. The measured data show that all the AMC surfaces act as good ground planes for a lowprofile antenna, yet the bandwidth and gain of the mushroom-like EBG structure are broader and larger, respectively, than those of the other structures.

This study reports on the synthesis and characterization of conducting polyaniline (PANI) thin films when using advanced atmospheric pressure plasma jets (APPJs). A simple method for synthesizing conducting polymers (CPs) with humidity-independent characteristics is introduced using advanced APPJs and an in-situ iodine doping method. In the case of ex-situ I 2 doping, a humidity effect study showed that increasing the relative humidity produced significant changes in the electrical resistance (R) of the PANI, indicating strong humidity-dependent characteristics similar to conventional CPs. In contrast, in the case of in-situ I 2 doping, the R and sensitivity of the PANI remained essentially unchanged when increasing the relative humidity, except for a very low sensitivity of 0.5% under 94% relative humidity. In addition, the R for the PANI with in-situ I 2 doping showed no aging effect, while the R for the ex-situ-doped PANI increased dramatically over time. Thus, it is anticipated that the use of in-situ doping during plasma polymerization can be widely used to design stable and high-performance CPs with humidity-independent characteristics for a variety of applications.

Although polymerized aniline (polyaniline, PANI) with and without iodine (I2) doping has already been extensively studied, little work has been done on the synthesis of PANI films using atmospheric pressure plasma (APP) deposition. Therefore, this study characterized pure and I2-doped PANI films synthesized using an advanced APP polymerization system. The I2 doping was conducted ex-situ and using an I2 chamber method following the APP deposition. The pure and I2-doped PANI films were structurally analyzed using field emission scanning electron microscope (FE-SEM), atomic force microscope (AFM), X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and time of flight secondary ion mass spectrometry (ToF-SIMS) studies. When increasing the I2 doping time, the plane and cross-sectional SEM images showed a decrease in the width and thickness of the PANI nanofibers, while the AFM results showed an increase in the roughness and grain size of the PANI films. Moreover, the FT-IR, XPS, and ToF-SIMS results showed an increase in the content of oxygen-containing functional groups and C=C double bonds, yet decrease in the C–N and C–H bonds when increasing the I2 doping time due to the reduction of hydrogen in the PANI films via the I2. To check the suitability of the conductive layer for polymer display applications, the resistance variations of the PANI films grown on the interdigitated electrode substrates were also examined according to the I2 doping time.

This work presents a study on the preparation of plasma-polymerized aniline (pPANI) nanofibers and nanoparticles by an intense plasma cloud type atmospheric pressure plasma jets (iPC-APPJ) device with a single bundle of three glass tubes. The nano size polymer was obtained at a sinusoidal wave with a peak value of 8 kV and a frequency of 26 kHz under ambient air. Discharge currents, photo-sensor amplifier, and optical emission spectrometer (OES) techniques were used to analyze the plasma produced from the iPC-APPJ device. Field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), gas chromatography-mass spectrometry (GC-MS), and gel permeation chromatography (GPC) techniques were used to analyze the pPANI. FE-SEM and TEM results show that pPANI has nanofibers, nanoparticles morphology, and polycrystalline characteristics. The FT-IR and GC-MS analysis show the characteristic polyaniline peaks with evidence that some quinone and benzene rings are broken by the discharge energy. GPC results show that pPANI has high molecular weight (Mw), about 533 kDa with 1.9 polydispersity index (PDI). This study contributes to a better understanding on the novel growth process and synthesis of uniform polyaniline nanofibers and nanoparticles with high molecular weights using the simple atmospheric pressure plasma polymerization technique.

The use of a guide-tube and bluff-body with an advanced atmospheric pressure plasma source is investigated for the low-temperature synthesis of single-crystalline high-density plasma polymerized pyrrole (pPPy) nano-materials on glass and flexible substrates. Three process parameters, including the position of the bluff-body, Ar gas flow rate, and remoteness of the substrate from the intense and broadened plasma, are varied and examined in detail. Plus, for an in-depth understanding of the flow structure development with the guide-tube and bluff-body, various numerical simulations are also conducted using the same geometric conditions as the experiments. As a result, depending on both the position of the bluff-body and the Ar gas flow rate, an intense and broadened plasma as a glow-like discharge was produced in a large area. The production of the glow-like discharge played a significant role in increasing the plasma energy required for full cracking of the monomers in the nucleation region. Furthermore, a remote growth condition was another critical process parameter for minimizing the etching and thermal damage during the plasma polymerization, resulting in single- and poly-crystalline pPPy nanoparticles at a low temperature with the proposed atmospheric pressure plasma jet device.