Abstract:The nonlinear cohesive law derived from the weak van der Waals force for carbon nanotube/polymer interfaces is incorporated in present study of CNT-reinforced composites.Carbon nanotubes can indeed improve the mechanical behavior of composite at the small strain, but such improvement disappears at relatively large strain because the completely debonded nanotubes behave like voids in the matrix and may even weaken the composite. The increase of interface adhesion between carbon nanotubes and polymer matrix may significantly improve the composite behavior at the large strain.
It is reported that a flat free surface of a stressed solid is configurationally unstable under chemical etching and the surface roughness grows with different rates for different spatial frequencies. The theory described in this Letter predicts that with a shallow chemical etching the roughness with spatial frequency below a critical value grows while the roughness of higher frequency decays. The theory was verified via an atomic force microscope experiment with aluminum. This study provides a simple experimental method to measure stress in metals and ceramics.
Debonding of particle/matrix interfaces can significantly affect the macroscopic behavior of composite material. We have used a nonlinear cohesive law for particle/matrix interfaces to study interface debonding and its effect on particulate composite materials subject to uniaxial tension. The dilute solution shows that, at a fixed particle volume fraction, small particles lead to hardening behavior of the composite while large particles yield softening behavior. Interface debonding of large particles is unstable since the interface opening (and sliding) displacement(s) may have a sudden jump as the applied strain increases, which is called the catastrophic debonding. A simple estimate is given for the critical particle radius that separates the hardening and softening behavior of the composite.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.