We present an extensive investigation of a new erosion and weathering proxy derived from the 10 Be(meteoric)/ 9 Be(stable) ratio in the Amazon River basin. This new proxy combines a radioactive atmospheric flux tracer, meteoric cosmogenic 10 Be, with 9 Be, a trace metal released by weathering. Results show that meteoric 10 Be concentrations ([ 10 Be]) and 10 Be/ 9 Be ratios increase by >30% from the Andes to the lowlands. We can calculate floodplain transfer times of 2-30 kyr from this increase. Intriguingly however, the riverine exported flux of meteoric 10 Be shows a deficit with respect to the atmospheric depositional 10 Be flux. Most likely, the actual area from which the 10 Be flux is being delivered into the mainstream is smaller than the basin-wide one. Despite this imbalance, denudation rates calculated from 10 Be/ 9 Be ratios from bed load, suspended sediment, and water samples from Amazon Rivers agree within a factor of 2 with published in situ 10 Be denudation rates. Erosion rates calculated from meteoric [ 10 Be], measured from depth-integrated suspended sediment samples, agree with denudation rates, suggesting that grain size-induced variations in [ 10 Be] are minimized when using such sampling material instead of bed load. In addition, the agreement between erosion and denudation rates implies minor chemical weathering intensity in most Amazon tributaries. Indeed, the Be-specific weathering intensity, calculated from mobilized 9 Be comprising reactive and dissolved fractions that are released during weathering, is constant at approximately 40% of the total denudation from the Andes across the lowlands to the Amazon mouth. Therefore, weathering in the Amazon floodplain is not detected. (2015), A test of the cosmogenic 10 Be(meteoric)/ 9 Be proxy for simultaneously determining basin-wide erosion rates, denudation rates, and the degree of weathering in the Amazon basin,

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Abstract:In 2015, an emergency state was declared in Bolivia when Poopó Lake dried up. Climate variability and the increasing need for water are potential factors responsible for this situation. Because field data are missing over the region, no statements are possible about the influence of mentioned factors. This study is a preliminary step toward the understanding of Poopó Lake drought using remote sensing data. First, atmospheric corrections for Landsat (FLAASH and L8SR), seven satellite derived indexes for extracting water bodies, MOD16 evapotranspiration, PERSIANN-CDR and MSWEP rainfall products potentiality were assessed. Then, the fluctuations of Poopó Lake extent over the last 26 years are presented for the first time jointly, with the mean regional annual rainfall. Three main droughts are highlighted between 1990 and 2015: two are associated with negative annual rainfall anomalies in 1994 and 1995 and one associated with positive annual rainfall anomaly in 2015. This suggests that other factors than rainfall influenced the recent disappearance of the lake. The regional evapotranspiration increased by 12.8% between 2000 and 2014. Evapotranspiration increase is not homogeneous over the watershed but limited over the main agriculture regions. Agriculture activity is one of the major factors contributing to the regional desertification and recent disappearance of Poopó Lake.

Land-use/cover change (LUCC) and climate change are major controlling factors for water resources in the Distrito Federal in Western Central Brazil. Dynamic LUCC in the region has severe impacts on water resources, while climate changes during the last three decades is thought to have only moderate effects. LUCC affects water quantity mostly during base flow conditions. River basins with substantial expansion of agriculture since the end 1970s show a dramatic decrease of base flow discharge by 40-70%, presumably due to irrigation. In contrast, the effects of urbanization on runoff are less distinct, since factors controlling runoff generation might be more variable. For water quality, we found urban areas to have a strong influence on the parameters CSB, NH 4 ? , and suspended solids. In addition, we assume emerging pollutants, e.g. organic (micro)pollutants, might play a major role in the future. The project IWAS-Á GUA DF focuses on creating the scientific base to face these problems in frame of an IWRM concept for the region. Results of our study will be a contribution to an IRWM concept for the Distrito Federal and will help to maintain high standards in water supply for the region.

This study assesses the performance of the new Global Precipitation Measurement (GPM)-based satellite precipitation estimates (SPEs) datasets in the Brazilian Central Plateau and compares it with the previous Tropical Rainfall Measurement Mission (TRMM)-era datasets. To do so, the Integrated Multi-satellitE Retrievals for GPM (IMERG)-v5 and the Global Satellite Mapping of Precipitation (GSMaP)-v7 were evaluated at their original 0.1° spatial resolution and for a 0.25° grid for comparison with TRMM Multi-satellite Precipitation Analysis (TMPA). The assessment was made on an annual, monthly, and daily basis for both wet and dry seasons. Overall, IMERG presents the best annual and monthly results. In both time steps, IMERG’s precipitation estimations present bias with lower magnitudes and smaller root-mean-square error. However, GSMaP performs slightly better for the daily time step based on categorical and quantitative statistical analysis. Both IMERG and GSMaP estimates are seasonally influenced, with the highest difficulty in estimating precipitation occurring during the dry season. Additionally, the study indicates that GPM-based SPEs products are capable of continuing TRMM-based precipitation monitoring with similar or even better accuracy than obtained previously with the widely used TMPA product.

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The Paraiba do Sul (PSR) and Guandu Rivers (GR) water diversion system (120 km long) is located in the main industrial pole of Brazil and supplies drinking water for 9.4 million people in the metropolitan region of Rio de Janeiro. This study aims to discern the trace metals dynamics in this complex aquatic system. We used a combined approach of geochemical tools such as geochemical partitioning, Zn isotopes signatures, and multivariate statistics. Zinc and Pb concentrations in Suspended Particulate Matter (SPM) and sediments were considerably higher in some sites. The sediment partition of As, Cr, and Cu revealed the residual fraction (F4) as the main fraction for these elements, indicating low mobility. Zinc and Pb were mostly associated with the exchangeable/carbonate (F1) and the reducible (F2) fractions, respectively, implying a higher susceptibility of these elements to being released from sediments. Zinc isotopic compositions of sediments and SPM fell in a binary mixing source process between lithogenic (δ66/64ZnJMC ≈ + 0.30‰) and anthropogenic (δ66/64ZnJMC ≈ + 0.15‰) end members. The lighter δ66/64ZnJMC values accompanied by high Zn concentrations in exchangeable/carbonate fraction (ZnF1) enable the tracking of Zn anthropogenic sources in the studied rivers. Overall, the results indicated that Hg, Pb, and Zn had a dominant anthropogenic origin linked to the industrial activities, while As, Cr, and Cu were mainly associated with lithogenic sources. This work Please note that this is an author-produced PDF of an article accepted for publication following peer review. The definitive publisher-authenticated version is available on the publisher Web site.demonstrates how integrating geochemical tools is valuable for assessing geochemical processes and mixing source effects in anthropized river watersheds.