Interior Antarctica is among the most remote places on Earth and was thought to be beyond the reach of human impacts when Amundsen and Scott raced to the South Pole in 1911. Here we show detailed measurements from an extensive array of 16 ice cores quantifying substantial toxic heavy metal lead pollution at South Pole and throughout Antarctica by 1889 – beating polar explorers by more than 22 years. Unlike the Arctic where lead pollution peaked in the 1970s, lead pollution in Antarctica was as high in the early 20th century as at any time since industrialization. The similar timing and magnitude of changes in lead deposition across Antarctica, as well as the characteristic isotopic signature of Broken Hill lead found throughout the continent, suggest that this single emission source in southern Australia was responsible for the introduction of lead pollution into Antarctica at the end of the 19th century and remains a significant source today. An estimated 660 t of industrial lead have been deposited over Antarctica during the past 130 years as a result of mid-latitude industrial emissions, with regional-to-global scale circulation likely modulating aerosol concentrations. Despite abatement efforts, significant lead pollution in Antarctica persists into the 21st century.

[1] Volcanic signatures in ice-core records provide an excellent means to date the cores and obtain information about accumulation rates. From several ice cores it is thus possible to extract a spatio-temporal accumulation pattern. We show records of electrical conductivity and sulfur from 13 firn cores from the Norwegian-USA scientific traverse during the International Polar Year 2007-2009 (IPY) through East Antarctica. Major volcanic eruptions are identified and used to assess century-scale accumulation changes. The largest changes seem to occur in the most recent decades with accumulation over the period 1963-2007/08 being up to 25% different from the long-term record. There is no clear overall trend, some sites show an increase in accumulation over the period 1963 to present while others show a decrease. Almost all of the sites above 3200 m above sea level (asl) suggest a decrease. These sites also show a significantly lower accumulation value than large-scale assessments both for the period 1963 to present and for the long-term mean at the respective drill sites. The spatial accumulation distribution is influenced mainly by elevation and distance to the ocean (continentality), as expected. Groundpenetrating radar data around the drill sites show a spatial variability within 10-20% over several tens of kilometers, indicating that our drill sites are well representative for the area around them. Our results are important for large-scale assessments of Antarctic mass balance and model validation.

The mass balance of Antarctica is one of the crucial factors for determining sea-level change in a warming climate. The marginal zones of the continent, namely the ice shelves, are most sensitive to climate change. During the 2009/10 austral summer an extensive glaciological field campaign was carried out on Fimbulisen, an ice shelf in East Antarctica, to investigate its recent surface mass balance. Shallow (10–18 m) firn cores were drilled and accumulation rates and stable-isotope ratios determined. For firn-core dating, two different methods were compared: (1) seasonal variations of stable oxygen isotope ratios (δ18O), and (2) dielectric profiling, including using the volcanic eruptions of Pinatubo, Philippines (1991), and El Chichόn, Mexico (1982), as time markers. The mean annual accumulation for the period 1992–2009 ranges from 298 to 349 mmw.e. a–1. The interannual variability at the drilling sites is >30%. Accumulation rates show a weak decreasing trend during the past 20–30 years, which is statistically significant only for one of the cores. Stable-isotope ratios were compared to the snowfall temperature of Neumayer station. Neither the temperatures nor the δ18O values show any trend for the investigated time period.

Abstract. Refractory black carbon aerosols (rBC) from biomass burning and fossil fuel combustion are deposited to the Antarctic ice sheet and preserve a history of emissions and long-range transport from low-and mid-latitudes.