Copper indium sulfide (CIS) quantum dots (QDs) with different Cu/In molar ratios of 1/1, 1/2, and 1/4 are synthesized via a hot colloidal route. The band gap energy of CIS QDs is observed to be dependent on Cu/In ratio, exhibiting a higher band gap from more Cu-deficient QDs. The emission wavelengths of all CIS QDs belong to a deep red region (665–717 nm) with relatively low quantum yields (QYs) of 8.6–12.7%. Compared to respective original core QDs, the absorption peaks of all CIS/ZnS QDs are blue-shifted, and their emission wavelengths move to a higher energy accordingly, showing a quite tunable emission from yellow to red. The effective surface passivation by a ZnS overlayer results in a dramatic increase in QY of CIS/ZnS QDs in the range of 68–78%. All CIS/ZnS QDs are tested as wavelength converters for the fabrication of QD-based light-emitting diodes (LEDs). QD-based white LEDs that consist of only a single type of QD are for the first time realized by applying yellow-emitting CIS/ZnS QDs as a result of the appropriate color mixing between blue emission from a LED chip and yellow emission from QDs. Detailed electroluminescent properties including color rendering index, Commission Internationale de l’Eclairage (CIE) color coordinates, and luminous efficiency of QD-based white LEDs are evaluated as a function of forward current.

Green CdSe@ZnS quantum dots (QDs) of 9.5 nm size with a composition gradient shell are first prepared by a single-step synthetic approach, and then 12.7 nm CdSe@ZnS/ZnS QDs, the largest among ZnS-shelled visible-emitting QDs available to date, are obtained through the overcoating of an additional 1.6 nm thick ZnS shell. Two QDs of CdSe@ZnS and CdSe@ZnS/ZnS are incorporated into the solution-processed hybrid QD-based light-emitting diode (QLED) structure, where the QD emissive layer (EML) is sandwiched by poly(9-vinlycarbazole) and ZnO nanoparticles as hole and electron-transport layers, respectively. We find that the presence of an additional ZnS shell makes a profound impact on device performances such as luminance and efficiencies. Compared to CdSe@ZnS QD-based devices the efficiencies of CdSe@ZnS/ZnS QD-based devices are overwhelmingly higher, specifically showing unprecedented values of peak current efficiency of 46.4 cd/A and external quantum efficiency of 12.6%. Such excellent results are likely attributable to a unique structure in CdSe@ZnS/ZnS QDs with a relatively thick ZnS outer shell as well as a well-positioned intermediate alloyed shell, enabling the effective suppression of nonradiative energy transfer between closely packed EML QDs and Auger recombination at charged QDs.

For colloidal quantum dot light-emitting diodes (QD-LEDs), blue emissive device has always been inferior to green and red counterparts with respect to device efficiency, primarily because blue QDs possess inherently unfavorable energy levels relative to green and red ones, rendering hole injection to blue QDs from neighboring hole transport layer (HTL) inefficient. Herein, unprecedented synthesis of blue CdZnS/ZnS core/shell QDs that exhibit an exceptional photoluminescence (PL) quantum yield of 98%, extraordinarily large size of 11.5 nm with a shell thickness of 2.6 nm, and high stability against a repeated purification process is reported. All-solution-processed, multilayered blue QD-LEDs, consisting of an HTL of poly(9-vinlycarbazole), emissive layer of CdZnS/ZnS QDs, and electron transport layer of ZnO nanoparticles, are fabricated. Our best device displays not only a maximum luminance of 2624 cd/m(2), luminous efficiency of 2.2 cd/A, and external quantum efficiency of 7.1%, but also no red-shift and broadening in electroluminescence (EL) spectra with increasing voltage as well as a spectral match between PL and EL.

Ultra-small (3.1 nm) multifunctional CdS:Mn/ZnS core-shell semiconductor quantum dots (Qdots), which possess fluorescent, radio-opacity, and paramagnetic properties, have been shown here. To demonstrate in vivo bioimaging capability, a rat was administered endovascularly with Qdots conjugated with a TAT peptide. The labeling efficacy of these Qdots was demonstrated on the basis of the histological analysis of the microtome sliced brain tissue, clearly showing that TAT-conjugated Qdots stained brain blood vessels.