This review showcases a comprehensive analysis of studies that highlight the different conversion procedures attempted across the globe. The resources of biogas production along with treatment methods are presented. The effect of different governing parameters like feedstock types, pretreatment approaches, process development, and yield to enhance the biogas productivity is highlighted. Biogas applications, for example, in heating, electricity production, and transportation with their global share based on national and international statistics are emphasized. Reviewing the world research progress in the past 10 years shows an increase of ~ 90% in biogas industry (120 GW in 2019 compared to 65 GW in 2010). Europe (e.g., in 2017) contributed to over 70% of the world biogas generation representing 64 TWh. Finally, different regulations that manage the biogas market are presented. Management of biogas market includes the processes of exploration, production, treatment, and environmental impact assessment, till the marketing and safe disposal of wastes associated with biogas handling. A brief overview of some safety rules and proposed policy based on the world regulations is provided. The effect of these regulations and policies on marketing and promoting biogas is highlighted for different countries. The results from such studies show that Europe has the highest promotion rate, while nowadays in China and India the consumption rate is maximum as a result of applying up-to-date policies and procedures.
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Two and three dimensional modeling of a single cell of vanadium redox flow battery has been done thoroughly according to electrochemical and fluid mechanic equations in this study. The modeling has been done in stationary state and its results have been presented in three chemical, electrical and mechanical sub models. The parametric analysis on some of important factors in cell operation demonstrated that increase in electrode and membrane conductivity and electrode porosity contributes to electric potential increase in cells. Also operational temperature increase leads to decrease in cells' voltage. Better fluid distribution on the electrode surface area results in better cell operation, therefore the electrolyte flow distribution form in cell has been studied by designing different flow frames. Modified Navier-Stokes equations have been used in these calculations for porous media. The most coverage on electrode surface and low pressure loss had been the best case criteria.
This study proposes a comprehensive data processing and modeling framework for building high-accuracy machine learning model to predict the steam consumption of a gas sweetening process. The data pipeline processes raw historical data of this application and identifies the minimum number of modeling variables required for this prediction in order to ease the applicability and practicality of such methods in the industrial units. On the modeling end, an empirical comparison of most of the state-of-the-arts regression algorithms was run in order to find the best fit to this specific case study. The ultimate goal is to leverage this model to identify the achievable energy conservation opportunity in such plants. The historical data for this modeling was collected from a gas treating plant at South Pars Gas Complex for 3 years from 2017 to 2019. This data gets passed through a multistage data processing scheme that conducts multicollinearity analysis and model-based feature selection. For model selection, a wide range of regression algorithms from different classes of regressor have been considered. Among all these methods, the Gradient Boosting Machines model outperformed the others and achieved the lowest crossvalidation error. The results show that this model can predict the steam consumption values with 98% R-squared accuracy on the holdout test set. Furthermore, the offline analysis demonstrates that there is a potential of 2% energy saving, equivalent to 24 000 metric tons of annual steam consumption reduction, which can be achieved by mapping the underperforming energy consumption states of the unit to the expected performances predicted by the model.
This study has considered hybrid system SOFC/GT with the new approach. This cycle, as a p ower plant is designed to reduce losses and improve comprehensive cycle performance. In the first part cycle, fluidized bed system with biomass (wood chips) fuel using gas cleaning mechanism, produce combustible gases which are required fuel combustion chambers of steam reformer and the GT. Second part cycle, required hydrogen for SOFC system is supplied through external SR. In the third part, the treated bio syn-gas from the cleaning unit outlet, in conjunction with recycled exhaust gases of the cell's anode will feed SR and GT combustors. In the fourth part cycle, flue gas would pass through heat recovery steam generator. Thus, high pressure and low pressure steams with values 3.39&0.45 ton/hr, respectively are generated. In this study, SOFC and GT with a capacity of 1000 & 750.81 kW respectively are designed. Overall efficiency of power production 74.4% is obtained. In comparison with similar study done in 2008 at the University of Delft, that overall 47% efficiency, increasing the efficiency of such systems has been viewed.
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