In this work, we synthesized a metal-free sulfonic functionalized graphitic carbon nitride using sulfuric acid through the wet impregnation technique. The functionalization of sulfonic groups (–SO3H) on g-C3N4 will promote a high surface charge density and charge separation owing to its high electronegativity. The g-C3N4–SO3H shows excellent optical/electronic and surface properties towards enhanced photo–redox reactions. The sulfonic groups also facilitate the availability of more separated charge carriers for photocatalytic oxidation and reduction reactions. The as-synthesized material has been characterized by different spectroscopic tools to confirm the presence of functionalized –SO3H groups and optoelectronic possessions. The photocatalytic responses of g-C3N4–SO3H result in 99.56% photoreduction of Cr (VI) and 99.61% photooxidation of Sunset Yellow FCF within 16 min and 20 min, respectively, of visible light irradiation. The g-C3N4–SO3H catalyst exhibits a high apparent rate constant (Kapp) towards the degradation of Cr (VI), and SSY, i.e., 0.783 min−1 and 0.706 min−1, respectively. The intense optical–electrochemical properties and potentially involved active species have been analyzed through transient photocurrent, electrochemical impedance, and scavenging studies. Consequently, the photocatalytic performances are studied under different reaction parameters, and the plausible photocatalytic mechanism is discussed based on the results.
Climate change, caused by greenhouse gas emissions, is one of the biggest threats to the world. As per the IEA report of 2021, global CO2 emissions amounted to around 31.5 Gt, which increased the atmospheric concentration of CO2 up to 412.5 ppm. Thus, there is an imperative demand for the development of new technologies to convert CO2 into value-added feedstock products such as alcohols, hydrocarbons, carbon monoxide, chemicals, and clean fuels. The intrinsic properties of the catalytic materials are the main factors influencing the efficiency of electrochemical CO2 reduction (CO2-RR) reactions. Additionally, the electroreduction of CO2 is mainly affected by poor selectivity and large overpotential requirements. However, these issues can be overcome by modifying heterogeneous electrocatalysts to control their morphology, size, crystal facets, grain boundaries, and surface defects/vacancies. This article reviews the recent progress in electrochemical CO2 reduction reactions accomplished by surface-defective electrocatalysts and identifies significant research gaps for designing highly efficient electrocatalytic materials.
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