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Removing water from wood is a critical requirement for applications in building and construction and for chemical modifications. Normally, green radiata pine (Pinus radiata D. Don) timber, with a moisture content (MC) range at harvest between 150% and 200%, is kiln dried to below fiber saturation point (FSP) to 10–14% MC. In the present work, a physical-chemical-mechanical dewatering process is presented, which involves pressure cycling with supercritical CO2 to remove water to near the FSP. When the CO2 was cycled from ∼4 MPa into the supercritical state, at pressures up to 20 MPa, specimens of cross-sectional dimensions of up to 52 mm were successfully dewatered from a MC of 174%, typical of the green state, to approximately 39% in seven cycles. The specimens with the smallest cross-sectional dimensions dewatered more slowly than the larger specimens. Preheating the green wood before loading it into the dewatering vessel increased the rate of dewatering. The final MCs were similar in all experiments and were independent of specimen dimension (15–52 mm) or preheating temperature between 40°C and 60°C. Pressure-temperature phase diagrams show that it is necessary to compress the CO2 to the supercritical state for efficient dewatering. Diffusion rates and solubility of CO2 in sap were important, but channel opening within specimens was proposed to be a critical factor in the dewatering process. The reason why pressure-based experiments remove water from wood to an MC greater than the established FSP of 30% is not yet clear.

Clear-coated boards have not been recommended for use in exterior conditions since irradiation with visible and UV radiation darkens them and photodegrades the lignin in the wooden surface beneath the coating, leading to delamination and subsequent catastrophic coating failure due to the continued action of sun, rain, and biological factors. Many approaches to rectify this problem have been explored. Chemical modification of the surface with hexavalent chromium, reaction with various anhydrides, grafting of UV absorbers, and esterification are among the methods attempted. A second approach has been via the clear coating itself where UV absorbers, antioxidants, and ultrafine titanium and iron oxides have been added. However, these have had limited or no success in stopping photodegradation processes. Since the main cause of photodegradation is photooxidation of lignin in the wooden surface as a consequence of free radical reactions initiated by UV irradiation, the approach taken in the present study, in an attempt to enhance the weathering performance of clear-coated boards outdoors, was to delignify the surfaces of wooden boards and then apply clear coatings to try and retard possible photodegradation. Two different pretreatments were used. Firstly, chemical surface delignification with a peracetic acid treatment created a partial delignification to a depth of 2-3 mm while still retaining the structural integrity of the surface. Secondly, a preweathering treatment, which resulted in a 100-lmdeep delignification zone, was compared. The coatings applied to the exposure surface of the pretreated boards were either polyurethane or an acrylic varnish. The clear-coated boards were exposed to exterior and accelerated weathering regimes for 3 years or 3000 h, respectively. Pretreated coated boards did not darken and yellow on exposure but untreated coated boards did. However, despite apparently arresting photodegradative processes on board surfaces, there were no significant gains in the performance ratings of coated pretreated boards over those of coated untreated control boards. Explanations for this involve the effectiveness of design factors incorporated into boards for exposure trials. These factors were the fungicidal dipping of boards before coating, precoating the exposure surface with a reactive primer, and applying a full polyurethane system to the back side and edges of boards. Both pretreatments resulted in clear-coated board surfaces that performed very similarly on exposure outperforming systems reported previously. It was surprising to observe that the preweathering treatment, which resulted in a 100-lm-deep delignification zone, performed as effectively as the chemically pretreated boards with 2-to 3-mm treatment zone. However, preweathered surfaces had lost all lignin in the middle lamella and there was cell separation, whereas in peracetic acid-treated boards, there was more or less complete lignin removal from the cell corner middle lamella only and partial lignin removal from other cell wall regions. ...

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