The usage of wastes of bagasse would be admirable from environmental and solid waste management point of view. Thus, herein, this data set present a facile method for providing an adsorbent from mixture of bagasse-bentonite. The prepared adsorbent was applied to remove Pb2+ from aqueous solution. It was conducted in laboratory scale using completely randomized design with variations in mixed mass ratio (1:0, 1:1, 1:2, 1:3, 2:1, 3:1), pH (2, 3, 4, 5, 6, 7) and contact time (5, 10, 30, 45, 90, 120, 180 min) and the adsorption technique was batch technique. The mixed adsorbent with 3:1 of mass ratio provided the highest Pb2+ adsorption efficiency of 97.31%. The optimum pH of Pb2+ adsorption was 5 and contact time was efficient at 45 min giving adsorption efficiency of 94.76% and 93.38%. The characterization data of the adsorbent were analyzed using XRF and FTIR methods. The XRF test results showed the changes of elemental content in adsorbent after the adsorption indicated that adsorbent can absorb Pb2+. The FTIR test results showed that adsorbent has a functional group that is useful in adsorption process. Adsorption of Pb2+ by adsorbent from mixture of bagasse-bentonite follows pseudo second order model with correlation coefficient value of 99.99% (R2 = 0.9999) and Freundlich isotherm model with correlation coefficient value of 90.05% (R2 = 0.9005). The acquired data indicated that the adsorption of Pb2+ by the adsorbent prepared from mixture of bagasse-bentonite is a promising technique for treating Pb-bearing wastewaters.
Although several approaches have been explored for the removal of dyes and other toxic materials from water as well as the entire environment, notwithstanding, researchers/scientists are still pursuing novel, low-cost, and eco-friendly biosorbents for the effective removal of such contaminants. Herein, clove leaves (CL) were utilized as a biosorbent for the sequestration of malachite green (MG) from a water-soluble solution. The CL was subsequently activated using potassium hydroxide (KOH) and characterized using the FTIR and FESEM to determine the functional groups on the activated clove leaves (CL-KOH) and the morphology of the adsorbent. The adsorption of MG was observed to be relatively dependent on the dosage of sorbent utilized, initial MG concentration, and sorption process contact time. The adsorption process of MG to CL was ideally described using the Dubinin–Radushkevich and Elovich models with the determination of maximum sorption capacity of approximately 131.6 mg·g-1. Furthermore, the thermodynamic parameters calculated showed that the adsorption of MG to the adsorbent was exothermic with the process involving physical sorption as well as chemical sorption processes with negligible adsorption energy. In conclusion, the study has revealed that the CL is a cost-effective biosorbent with high adsorption efficiency for the sequestration of MG from a water-soluble solution and can be recycled for further usage.
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