Aerogels are predominantly mesoporous, extremely lightweight, low density (∼ 0.003 g/cm3) and thermally insulating materials. Over the years, aerogels have gained increasing attention due to their extraordinary properties (light, heat, sound, electricity and force) and application potentials in varieties of fields. Several studies have been carried out regarding aerogel preparation and its applications in coatings on different substrates. In this review, an overview of aerogels preparation and their application progress in coatings of most common substrates is presented. Attention is paid to aerogel coatings of textiles, leather, and substrates other than leather and textiles for special functionalities that could address the application progress in coatings. This review will help to inspire scientists and engineers towards novel aerogel materials and technologies to boost the industrial fabrication of flexible advanced materials.
Engineering high-performance chrome-free colored leather is currently a tough challenge in the leather industry. Herein, we report on a novel tanning−dyeing integration strategy based on converting natural cochineal carmine (Car) into an effective tanning agent (DCar) without losing its dyeing capabilities via periodate oxidation. Initially, DCar was used as a tanning−dyeing agent, leading to tanned-dyed leather with well-dispersed and fixed collagen fibers (CFs) and a shrinkage temperature (T s ) of ca. 70 °C. Subsequently, this leather was filled and fatliquored to be prepared for the subsequent aluminum fixation of the CFs matrix, which was facilitated by the excellent metal complexation capabilities of DCar. This dual integrative process resulted in successful simultaneous leather tanning and dyeing. Consequently, the resultant crust leather had a T s of ca. 80 °C with an outstandingly dispersed and fixed CFs network and excellent softness, fullness, and commercializable mechanical strength (tensile strength: 13 N/mm 2 ; tear strength: 54 N/mm). Besides, it also had a highly marketable brown color, a smooth grain surface, and excellent coloring uniformity and fastness. These results open the door for a new paradigm, i.e., providing natural pigments and dyes with tanning properties to develop novel and benign dual tanning− dyeing agents for the leather industry.
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