Two synthetic base oils (815Z and 2001A) and two greases (601EF and R2000) used for space applications have been studied at ground level. Rheological tests were performed in order to characterize the behavior of each of the base oils versus the pressure and the temperature. Next, the effect of base oils and greases on ball bearing fatigue life was carried out using thrust ball bearings. The results of L 10 life tests showed a bearing life order from the highest to the lowest of grease 601EF (blended with base oil 815Z), base oil 2001A, grease R2000 (blended with the base oil 2001A) and, the lowest, the base oil 815Z. The general tendency of the base oils and the greases shows that the bearing life increases with the EHL film parameter. However, the anticipated beneficial effect of an apparently high film parameter for the base oil 815Z was not seen due to permanent viscosity loss in the EHL contact. The results showed that the viscosity of the base oil 815Z, which contains the acetal group , was decreased by mechanical shear at the high shear rate in the EHL conjunction and the EHL oil film was thinner than expected. Hydrogen fluoride is released with the decomposition of the acetal group. As a result, the permanent viscosity loss at high Hertzian pressure and the hydrogen fluoride generation shortened bearing life with the 815Z base oil. In the case of grease 601EF with base oil 815Z, the permanent viscosity loss did not occur in ball bearings and the bearing life is extended.
An unbranched perfluoropolyether (PFPE) 815Z is the current ball bearing lubricant for space applications. Measurements of elastohydrodynamic lubrication (EHL) oil film thickness have been carried out to assess the lubricating performance of PFPE with average molecular weight of 9200 using an optical interferometric technique under mean Hertzian pressure 0.45 GPa. The film thickness of 815Z became less than predicted film thickness from Hamrock and Dowson formula for EHL central film thickness. There are two main explanations why PFPE is inferior to mineral oil in their ability to form EHL films, temporary viscosity loss and permanent viscosity loss. In order to elucidate the results, measurements of permanent viscosity loss under mean Hertzian pressure from 0.41 GPa to 2.67 GPa have been carried out using the thrust ball bearing. There results show that the degree of the permanent viscosity loss depends on Hertzian pressure, occurrence of permanent viscosity loss of 36 % with 2.67 GPa and 2 % with 0.41 GPa.
We attempted to reduce false-positives during screening for neuroblastoma using a qualitative urine test by introducing a test diet without foodstuffs known to cause false-positive results. In preliminary in-vivo experiments, intake of contra-indicated foods such as orange juice or banana was shown to result in high percentages of false-positive results several hours after food intake. False-positive results were obtained even after 24 hours among breast-fed infants whose mothers received orange juice. In a controlled field trial the false-positive rate was reduced to 2.84% among 540 infants taking the test diet compared with 5.05% among 9,844 control infants following conventional guidance on contra-indicated foods (p less than 0.05). For comparison, a questionnaire survey of nationwide screening in Japan in 1987 revealed that 66% of the screening centres employed qualitative urine tests, either a Spot or Dip method. False-positive rates, including those due to inappropriate urine collection, ranged from 0.4% to 33.7% (mean 7.1%). Rates ranged from 0.2% to 18.7% (mean 3.4%) in the remaining 34% of screening centres employing a quantitative method with high performance liquid chromatography.
Rev., 16, 285 (1975).2) idem: J. Chromatograph, 105, 141 (1975 Ser., 71, 136 (1975).9) Hughes, M. A., H. C. Sergeant, R. J. Whewell: /. Inorg. Nucl. Chem., 41, 1603 (1979. 10) Kataoka, T., T. Nishiki, Y. Tamura and K. Ueyama: /.Chem. Eng. Japan, 13, 35 (1980). ll) Kojima, T., J. Tomita and T. Miyauchi: KagakuKogaku Ronbunshu, 5, 476 (1979). 12) Komasawa, I., T. Otake and A. Yamada: /. Chem. Eng. Japan, 13, 130 (1980 A method to estimate the composition of solid condensate from a binary vapor in fractional sublimation accompanied by an entrainer gas is derived, including an overall coefficient for condensation of the individual components. The coefficient was empirically correlated with gas flow rates, surface temperatures of condenser, and condenser dimensions. Good agreement between the estimated and observed compositions of the condensates was obtained for two eutectic-forming organic mixtures and one solid solution organic mixture.
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