The surface modifications induced by treating Cu(In,Ga)(S,Se)2 films in an aqueous ammonia hydroxide-based solution of Cd2+ ions—as used in record Cu(In,Ga)(S,Se)2 solar cells without a CdS buffer layer—have been investigated for different Cd2+ concentrations. Employing a combination of x-ray photoelectron spectroscopy, Auger electron spectroscopy, and x-ray emission spectroscopy, it is possible to distinguish two different surface modifications. For Cd2+ concentrations below 4.5 mM in the solution we observe the formation of a CdS monolayer, while higher Cd2+ concentrations lead to the additional deposition of a cadmium hydroxide film on the CdS/Cu(In,Ga)(S,Se)2 surface.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.