In this work, we introduce the application of gas diffusion electrodes (GDE) for benchmarking the electrocatalytic performance of high surface area fuel cell catalysts.
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It's a knockout! When the surface of gold electrodes is treated with hydroxyl radicals, the electron‐transfer rates ks of electrochemical reactions involving radical intermediates are drastically reduced (see picture). This observation can be explained by the selective knockout of gold active sites associated with partially filled d orbitals.
IrOx-networks exhibit excellent catalytic activity towards oxygen evolution in acid media. A novel alternating sputtering process enabled simple and scalable fabrication of self-supported and highly dispersed iridium networks.
The development of catalysts for the oxygen reduction reaction in low-temperature fuel cells depends on efficient and accurate electrochemical characterization methods. Currently, two primary techniques exist: rotating disk electrode (RDE) measurements in half-cells with liquid electrolyte and single cell tests with membrane electrode assemblies (MEAs). While the RDE technique allows for rapid catalyst benchmarking, it is limited to electrode potentials far from operating fuel cells. On the other hand, MEAs can provide direct performance data at realistic conditions but require specialized equipment and large quantities of catalyst, making them less ideal for early-stage development. Using sputtered platinum thin-film electrodes, we show that gas diffusion electrode (GDE) half-cells can be used as an intermediate platform for rapid benchmarking at fuel-cell relevant current densities (~1 A cm−2). Furthermore, we demonstrate how different parameters (loading, electrolyte concentration, humidification, and Nafion membrane) influence the performance of unsupported platinum catalysts. The specific activity could be measured independent of the applied loading at potentials down to 0.80 VRHE reaching a value of 0.72 mA cm−2 at 0.9 VRHE in the GDE. By comparison with RDE measurements and Pt/C measurements, we establish the importance of catalyst characterization under realistic reaction conditions.
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