Graphene nanosheets were produced in large quantity via a soft chemistry synthetic route involving graphite oxidation, ultrasonic exfoliation, and chemical reduction. X-ray diffraction and transmission electron microscopy (TEM) observations show that graphene nanosheets were produced with sizes in the range of tens to hundreds of square nanometers and ripple-like corrugations. High resolution TEM (HRTEM) and selected area electron diffraction (SAED) analysis confirmed the ordered graphite crystal structure of graphene nanosheets. The optical properties of graphene nanosheets were characterized by Raman spectroscopy.
Polymer electrolytes have attracted great interest for next-generation lithium (Li)-based batteries in terms of high energy density and safety. In this review, we summarize the ion-transport mechanisms, fundamental properties, and preparation techniques of various classes of polymer electrolytes, such as solvent-free polymer electrolytes (SPEs), gel polymer electrolytes (GPEs), and composite polymer electrolytes (CPEs). We also introduce the recent advances of non-aqueous Li-based battery systems, in which their performances can be intrinsically enhanced by polymer electrolytes. Those include high-voltage Liion batteries, flexible Li-ion batteries, Li-metal batteries, lithium-sulfur (Li-S) batteries, lithium-oxygen (Li-O 2 ) batteries, and smart Li-ion batteries. Especially, the advantages of polymer electrolytes beyond safety improvement are highlighted. Finally, the remaining challenges and future perspectives are outlined to provide strategies to develop novel polymer electrolytes for high-performance Li-based batteries.
2D transition metal carbides and nitrides, named MXenes, are attracting increasing attentions and showing competitive performance in energy storage devices including electrochemical capacitors, lithium- and sodium-ion batteries, and lithium-sulfur batteries. However, similar to other 2D materials, MXene nanosheets are inclined to stack together, limiting the device performance. In order to fully utilize MXenes' electrochemical energy storage capability, here, processing of 2D MXene flakes into hollow spheres and 3D architectures via a template method is reported. The MXene hollow spheres are stable and can be easily dispersed in solvents such as water and ethanol, demonstrating their potential applications in environmental and biomedical fields as well. The 3D macroporous MXene films are free-standing, flexible, and highly conductive due to good contacts between spheres and metallic conductivity of MXenes. When used as anodes for sodium-ion storage, these 3D MXene films exhibit much improved performances compared to multilayer MXenes and MXene/carbon nanotube hybrid architectures in terms of capacity, rate capability, and cycling stability. This work demonstrates the importance of MXene electrode architecture on the electrochemical performance and can guide future work on designing high-performance MXene-based materials for energy storage, catalysis, environmental, and biomedical applications.
Designing atomically dispersed metal catalysts for oxygen reduction reaction (ORR) is a promising approach to achieve efficient energy conversion. Herein, we develop a template-assisted method to synthesize a series of single metal atoms anchored on porous N,S-codoped carbon (NSC) matrix as highly efficient ORR catalysts to investigate the correlation between the structure and their catalytic performance. The structure analysis indicates that an identical synthesis method results in distinguished structural differences between Fe-centered single-atom catalyst (Fe-SAs/NSC) and Co-centered/Ni-centered single-atom catalysts (Co-SAs/NSC and Ni-SAs/NSC) because of the different trends of each metal ion in forming a complex with the N,S-containing precursor during the initial synthesis process. The Fe-SAs/NSC mainly consists of a well-dispersed FeN 4 S 2 center site where S atoms form bonds with the N atoms. The S atoms in Co-SAs/NSC and Ni-SAs/NSC, on the other hand, form metal−S bonds, resulting in CoN 3 S 1 and NiN 3 S 1 center sites. Density functional theory (DFT) reveals that the FeN 4 S 2 center site is more active than the CoN 3 S 1 and NiN 3 S 1 sites, due to the higher charge density, lower energy barriers of the intermediates, and products involved. The experimental results indicate that all three single-atom catalysts could contribute high ORR electrochemical performances, while Fe-SAs/NSC exhibits the highest of all, which is even better than commercial Pt/C. Furthermore, Fe-SAs/NSC also displays high methanol tolerance as compared to commercial Pt/C and high stability up to 5000 cycles. This work provides insights into the rational design of the definitive structure of single-atom catalysts with tunable electrocatalytic activities for efficient energy conversion.
One-dimensional (1D) nanostructured materials have received considerable attention for advanced functional systems as well as extensive applications owing to their attractive electronic, optical, and thermal properties. [1][2] In lithium-ion-battery science, recent research has focused on nanoscale electrode materials to improve electrochemical performance. The high surface-to-volume ratio and excellent surface activities of 1D nanostructured materials have stimulated great interest in their development for the next generation of power sources. [3][4] Materials based on tin oxide have been proposed as alternative anode materials with high-energy densities and stable capacity retention in lithium-ion batteries. [5][6][7] Various SnO 2 -based materials have displayed extraordinary electrochemical behavior such that the initial irreversible capacity induced by Li 2 O formation and the abrupt capacity fading caused by volume variation could be effectively reduced when in nanoscale form. [8][9][10] From this point of view, SnO 2 nanowires can also be suggested as a promising anode material because the nanowire structure is of special interest with predictions of unique electronic and structural properties. Furthermore, the nanowires can be easily synthesized by a thermal evaporation method. However, in its current form, this method of manufacture of SnO 2 nanowires has several limitations: it is inappropriate for mass production as high synthesis temperatures are required and there are difficulties in the elimination of metal catalysts that could act as impurities or defects. This results in reversible capacity loss or poor cyclic performance during electrochemical reactions. [11,12] The critical issues relating to SnO 2 nanowires as anode materials for lithium-ion batteries are how to avoid the deteriorative effects of catalysts and how to increase production.Herein, we report on the preparation and electrochemical performance of self-catalysis-grown SnO 2 nanowires to determine their potential use as an anode material for lithium-ion batteries. SnO 2 nanowires have been synthesized by thermal evaporation combined with a self-catalyzed growth procedure by using a ball-milled evaporation material to increase production at lower temperature and prevent the undesirable effects of conventional catalysts on electrochemical performance. The self-catalysis-grown SnO 2 nanowires show higher initial coulombic efficiency and an improved cyclic retention compared with those of SnO 2 powder and SnO 2 nanowires produced by Au-assisted growth.[11]The self-catalysis growth method, which uses a ball-milled mixture of SnO and Sn powder as an evaporation source, is appropriate for obtaining SnO 2 nanowires with high purity. The deposited products on the Si substrates contain almost 100 % of the SnO 2 nanowires formed. Observation with scanning electron microscopy (SEM) clearly shows a general view of randomly aligned SnO 2 nanowires with diameters of 200-500 nm and lengths extending to several tens of micrometers (Figure 1 a). Sn drop...
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