Redox flow batteries are receiving wide attention for electrochemical energy storage due to their unique architecture and advantages, but progress has so far been limited by their low energy density (~25 Wh l−1). Here we report a high-energy density aqueous zinc-polyiodide flow battery. Using the highly soluble iodide/triiodide redox couple, a discharge energy density of 167 Wh l−1 is demonstrated with a near-neutral 5.0 M ZnI2 electrolyte. Nuclear magnetic resonance study and density functional theory-based simulation along with flow test data indicate that the addition of an alcohol (ethanol) induces ligand formation between oxygen on the hydroxyl group and the zinc ions, which expands the stable electrolyte temperature window to from −20 to 50 °C, while ameliorating the zinc dendrite. With the high-energy density and its benign nature free from strong acids and corrosive components, zinc-polyiodide flow battery is a promising candidate for various energy storage applications.
This work demonstrates a platform for designing a photocatalyst to promote lightdriven production of hydrogen from water. The newly developed photocatalyst consists of all sp 2 carbon frameworks that are fully p conjugated to promote exciton migration and offer a narrow band gap to harvest visible and near-infrared light. Engineering the lattice periphery with electron-deficient units tunes the band structure and constitutes built-in interfaces to generate electrons. The resulting frameworks enable efficient, continuous, and stable hydrogen production under irradiation.
Polymeric or organic semiconductors are promising candidates for photocatalysis but mostly only show moderate activity owing to strongly bound excitons and insufficient optical absorption. Herein, we report a facile bottom-up strategy to improve the activity of a carbon nitride to a level in which a majority of photons are really used to drive photoredox chemistry. Co-condensation of urea and oxamide followed by post-calcination in molten salt is shown to result in highly crystalline species with a maximum π-π layer stacking distance of heptazine units of 0.292 nm, which improves lateral charge transport and interlayer exciton dissociation. The addition of oxamide decreases the optical band gap from 2.74 to 2.56 eV, which enables efficient photochemistry also with green light. The apparent quantum yield (AQY) for H evolution of optimal samples reaches 57 % and 10 % at 420 nm and 525 nm, respectively, which is significantly higher than in most previous experiments.
Polymeric carbon nitride (PCN), in either triazine or heptazine form, has been regarded as a promising metal-free, environmentally benign, and sustainable photocatalyst for solar hydrogen production. However, PCN in most cases only exhibits moderate activity owing to its inherent properties, such as rapid charge carrier recombination. Herein we present a triazine-heptazine copolymer synthesized by simple post-calcination of PCN in eutectic salts, that is, NaCl/KCl, to modulate the polymerization process and optimize the structure. The construction of an internal triazine-heptazine donor-acceptor (D-A) heterostructure was affirmed to significantly accelerate interface charge transfer (CT) and thus boost the photocatalytic activity (AQY=60 % at 420 nm). This study highlights the construction of intermolecular D-A copolymers in NaCl/KCl molten salts with higher melting points but in the absence of lithium to modulate the chemical structure and properties of PCN.
Magnesium battery is potentially a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited performance and the lack of fundamental understandings of electrolytes. Here, we present a study in understanding coordination chemistry of Mg(BH4)2 in ethereal solvents. The O donor denticity, i.e. ligand strength of the ethereal solvents which act as ligands to form solvated Mg complexes, plays a significant role in enhancing coulombic efficiency of the corresponding solvated Mg complex electrolytes. A new electrolyte is developed based on Mg(BH4)2, diglyme and LiBH4. The preliminary electrochemical test results show that the new electrolyte demonstrates a close to 100% coulombic efficiency, no dendrite formation, and stable cycling performance for Mg plating/stripping and Mg insertion/de-insertion in a model cathode material Mo6S8 Chevrel phase.
Aqueous rechargeable
batteries are desirable for energy storage
because of their low cost and high safety. However, low capacity and
short cyclic life are significant obstacles to their practical applications.
Here, we demonstrate a highly reversible aqueous zinc–iodine
battery using encapsulated iodine in microporous carbon as the cathode
material by controlling solid–liquid conversion reactions.
We identified the factors influencing solid–liquid conversion
reactions, e.g., the pore size, surface chemistry of carbon host,
and solvent effect. Rational manipulation of the competition between
the adsorption in carbon and solvation in electrolytes for iodine
species is responsible for the high reversibility and cyclic stability.
The zinc–iodine battery delivers a high capacity of 174.4 mAh
g–1 at 1C, stable cyclic life over 3000 cycles with
∼90% capacity retention, and negligible self-discharge. We
believe that the principles for stabilizing the zinc–iodine
system could provide new insight for other conversion systems such
as lithium–sulfur systems.
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