Interlayer rotation and stacking were recently demonstrated as effective strategies for tuning physical properties of various two-dimensional materials. The latter strategy was mostly realized in heterostructures with continuously varied stacking orders, which obscure the revelation of the intrinsic role of a certain stacking order in its physical properties. Here, we introduce inversion-domain-boundaries into molecular-beam-epitaxy grown MoSe2 homobilayers, which induce uncommon fractional lattice translations to their surrounding domains, accounting for the observed diversity of large-area and uniform stacking sequences. Low-symmetry stacking orders were observed using scanning transmission electron microscopy and detailed geometries were identified by density functional theory. A linear relation was also revealed between interlayer distance and stacking energy. These stacking sequences yield various energy alignments between the valence states at the Γ and K points of the Brillouin zone, showing stacking-dependent bandgaps and valence band tail states in the measured scanning tunneling spectroscopy. These results may benefit the design of two-dimensional multilayers with manipulable stacking orders
The magnetic properties of carbon materials are at present the focus of intense research effort in physics, chemistry and materials science due to their potential applications in spintronics and quantum computing. Although the presence of spins in open-shell nanographenes has recently been confirmed, the ability to control magnetic coupling sign has remained elusive but highly desirable. Here, we demonstrate an effective approach of engineering magnetic ground states in atomically precise open-shell bipartite/nonbipartite nanographenes using combined scanning probe techniques and mean-field Hubbard model calculations. The magnetic coupling sign between two spins was controlled via breaking bipartite lattice symmetry of nanographenes. In addition, the exchange-interaction strength between two spins has been widely tuned by finely tailoring their spin density overlap, realizing a large exchange-interaction strength of 42 meV. Our demonstrated method provides ample opportunities for designer above-room-temperature magnetic phases and functionalities in graphene nanomaterials.
Autofocus has attracted wide attention for unmanned aerial vehicle (UAV) synthetic aperture radar (SAR) systems, because autofocus process is crucial and difficult when the phase error is spatially dependent on both range and azimuth directions. In this paper, a novel two-dimensional spatial-variant map-drift algorithm (2D-SVMDA) is developed to provide robust autofocusing performance for UAV SAR imagery. This proposed algorithm combines two enhanced map-drift kernels. On the one hand, based on the azimuth-dependent phase correction, a novel azimuth-variant map-drift algorithm (AVMDA) is established to model the residual phase error as a linear function in the azimuth direction. Then the model coefficients are efficiently estimated by a quadratic Newton optimization with modified maximum cross-correlation. On the other hand, by concatenating the existing range-dependent map-drift algorithm (RDMDA) and the proposed AVMDA in this paper, a phase autofocus procedure of 2D-SVMDA is finally established. The proposed 2D-SVMDA can handle spatial-variance problems induced by strong phase errors. Simulated and real measured data are employed to demonstrate that the proposed algorithm compensates both the range- and azimuth-variant phase errors effectively.
Deposition of Bi on InSb(111)B reveals a striking Sierpiński-triangle (ST)-like structure in Bi thin films. Such a fractal geometric topology is further shown to turn off the intrinsic electronic topology in a thin film. Relaxation of a huge misfit strain of about 30% to 40% between Bi adlayer and substrate is revealed to drive the ST-like island formation. A Frenkel-Kontrova model is developed to illustrate the enhanced strain relief in the ST islands offsetting the additional step energy cost. Besides a sufficiently large tensile strain, forming ST-like structures also requires larger adlayer-substrate and intra-adlayer elastic stiffnesses, and weaker intra-adlayer interatomic interactions.
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