Toward improving the selective adsorption performance of molecularly imprinted polymers in strong polar solvents, in this work, a new ionic liquid functional monomer, 1‐butyl‐3‐vinylimidazolium bromide, was used to synthesize sulfamethoxazole imprinted polymer in methanol. The resulting molecularly imprinted polymer was characterized by Fourier transform infrared spectra and scanning electron microscopy, and the rebinding mechanism of the molecularly imprinted polymer for sulfonamides was studied. A static equilibrium experiment revealed that the as‐obtained molecularly imprinted polymer had higher molecular recognition for sulfonamides (e.g., sulfamethoxazole, sulfamonomethoxine, and sulfadiazine) in methanol; however, its adsorption of interferent (e.g., diphenylamine, metronidazole, 2,4‐dichlorophenol, and m‐dihydroxybenzene) was quite low. 1H NMR spectroscopy indicated that the excellent recognition performance of the imprinted polymer was based primarily on hydrogen bond, electrostatic and π‐π interactions. Furthermore, the molecularly imprinted polymer can be employed as a solid phase extraction sorbent to effectively extract sulfamethoxazole from a mixed solution. Combined with high‐performance liquid chromatography analysis, a valid molecularly imprinted polymer‐solid phase extraction protocol was established for extraction and detection of trace sulfamethoxazole in spiked soil and sediment samples, and with a recovery that ranged from 93–107%, and a relative standard deviation of lower than 9.7%.
Light-driven actuators
that directly convert light into mechanical work have attracted significant
attention due to their wireless advantage and ability to be easily
controlled. However, a fundamental impediment to their application
is that the continuous motion of light-driven flexible actuators usually
requires a periodically switching light source or the coordination
of other additional hardware. Here, for the first time, continuous
flapping-wing motion under sunlight is realized through the utilization
of a simple nanocrystalline metal polymer bilayer structure without
the coordination of additional hardware. The light-driven performance
can be controlled by adjusting the grain size of the upper nanocrystalline
metallic layer or selecting metals with different thermodynamic parameters.
The achieved highest frequency of flapping-wing motion is 4.49 Hz,
which exceeds the frequency of real butterfly wings, thus informing
the further development of sunlight-driven bionic flying animal robotics
without external energy consumption. The flapping-wing motion has
been used to realize a light-driven whirligig, a light-driven sailboat,
and photoelectric energy harvesting. Furthermore, the flexible bilayer
actuator features the ability to be driven by light and electricity,
low-power actuation, a large deflection, fast actuation speed, long-time
stability, strong design ability, and large-area facile fabrication.
The bilayer film considered herein represents a simple, general, and
effective strategy for preparing photoelectric-driven flexible actuators
with target performances and informs the standardization and industrial
application of flexible actuators in the future.
mechanical energy harvesting, [3] and selfpowered sensing, [4] even in extreme scenarios such as fireground. [5] In recent years, a novel DC-TENG based on triboelectrification effect and electrostatic breakdown was reported, [6] based on which a motion vector sensor with high sensitivity was developed. [7] However, most traditional self-powered sensors usually work in direct contact mode or deformation mode, [8] which inevitably influences their sensing stability and shortens their service life due to long-term contact-induced wear. On the other hand, non-contact sensors/devices in public places, such as stations and hospitals, could effectively avoid the spread of infectious viruses/bacteria. [9] Therefore, it has huge significance and wide application prospects for developing non-contact sensors.The earliest non-contact triboelectric nanogenerator (NC-TENG) is the freerotating disk structure first proposed by Wang and his team in 2014, [10] which exhibits higher stability and durability compared to its working in contact mode. Then, Zhang et al. [11] proposed a self-powered vibration sensor with contact mode and non-contact mode, which would protect the device and the detected object in operation and the stability and repeatability could be well retained. In recent years, the Maxwell displacement current generated by the leakage field has proved to be the fundamental theoretical basis and source of TENG. [12] An electrodeless TENG based on Maxwell displacement current for wireless energy transmission was proposed, [13] Sensors as the significant units of the Internet of Things play an important role in the field of information interaction. Non-contact sensors have the advantages of flexible manipulation and a longer lifespan but it is constrained in motion detection due to their relative single detection function. Herein, a self-powered non-contact motion vector sensor (NMVS) for the multifunctional human-machine interface is reported. Based on the electrostatic induction effect, the motion vector is measured according to the output electrical signals from the non-contact triboelectric nanogenerator (NC-TENG). By simulation analysis and experimental validation, the output characteristics of NC-TENG dependence on structural and motion parameters are investigated in detail. On this basis, the resolution of NMVS is improved and exhibits for non-contact micro-vibration monitoring, rehabilitation gait detection, contactless smart lock, and the non-contact limit alarm. This work not only proposes an ingenious strategy for non-contact motion vector detection but also demonstrates the promising prospects of a multifunctional humanmachine interface in intelligent electronics, health rehabilitation, and industrial inspection.
Recent research achievements for flexible pressure sensors have promoted promising applications, such as human health detection and intelligent robotics. However, striking a balance between sensitivity and linear detection range is still a challenge. In this paper, a dual conductive layer dome (DCLD) structure, where a silver (Ag) nanowire layer is used as a highly conductive layer and the composite layer of carbon black nanoparticles and polydimethylsiloxane (CPDMS) serves as a low conductive layer, is fabricated with a scratch coating process followed by dip-coating and vacuum adsorption. Benefitting from the dual conductive layer design, the sensitivity of the DCLD sensor reaches 51.7 kPa −1 over an ultrawide pressure of 0.01−250 kPa, which is far better than the CPDMS single conductive layer dome (SCLD). The circuit models of DCLD and SCLD are proposed to disclose their working mechanism. The effects of carbon black nanoparticle ratio in CPDMS and the structural matching between the DCLD structure and electrode on the sensor's performance are explored. The long-cycle stability of DCLD sensors with different fabrication methods is also compared. Additionally, it has been demonstrated that the sensor is efficient in monitoring human motion, such as finger joint flexion, pulse pulses, and human breathing, showing potential in the field of human health monitoring.
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