For more information on the USGS-the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment, visit http://www.usgs.gov or call 1-888-ASK-USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprodTo order this and other USGS information products, visit http://store.usgs.gov Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted materials contained within this report.Suggested reference: Dubrovsky, N.M., Burow, K.R., Clark, G.M., Gronberg, J.M., Hamilton P.A., Hitt, K.J., Mueller, D.K., Munn, M.D., Nolan, B.T., Puckett, L.J., Rupert, M.G., Short, T.M., Spahr, N.E., Sprague, L.A., and Wilber, W.G., 2010, The quality of our Nation's waters-Nutrients in the Nation's streams and groundwater, 1992-2004: U.S. Geological Survey Circular 1350, 174 p. Additional information about this study is available at http://water.usgs.gov/nawqa/nutrients/pubs/circ1350 Library of Congress Cataloging-in-Publication DataThe quality of our Nation's waters : nutrients in the Nation's streams and groundwater, 1992-2004 ForewordThe U.S. Geological Survey (USGS) is committed to providing the Nation with reliable scientific information that helps to enhance and protect the overall quality of life and that facilitates effective management of water, biological, energy, and mineral resources (http://www.usgs.gov/). Information on the Nation's water resources is critical to ensuring long-term availability of water that is safe for drinking and recreation and is suitable for industry, irrigation, and fish and wildlife. Population growth and increasing demands for water make the availability of that water, now measured in terms of quantity and quality, even more essential to the long-term sustainability of our communities and ecosystems.The USGS implemented the National Water-Quality Assessment (NAWQA) Program in 1991 to support national, regional, state, and local information needs and decisions related to water-quality management and policy (http://water.usgs.gov/nawqa). The NAWQA Program is designed to answer: What is the quality of our Nation's streams and groundwater? How are conditions changing over time? How do natural features and human activities affect the quality of streams and groundwater, and where are those effects most pronounced? By combining information on water chemistry, physical characteristics, stream habitat, and aquatic life, the NAWQA Program aims to provide science-based insights for current and emerging water issues and priorities. From 1991to 2001, the NAWQA Program completed interdisciplinary assessments and established a baseline understanding of waterquality conditions in 51 of the Nation's river basins and aquifers, referred to as Study Units (http://water.usgs.gov/nawqa/studyu.ht...

Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flowweighted concentrations during 1990-95 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow-weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8

Galena Creek rock glacier (GCRG), northwest Wyoming, exhibits most of the classic characteristics of rock glaciers. Clean ice with silty bands was found beneath a c. 1 m thick debris mantle by Potter. He inferred that the ice is glacigenic, originating in the small snowfield in the cirque at the head of GCRG. This view was challenged by Barsch, who asserted that the ice in GCRG is of "permafrost" origin. Since then GCRG has become a lightning rod for opponents and proponents of the glacigenic ice model for rock glaciers. We review evidence for that model here.Movement marks emplaced on GCRG in the 1960s were resurveyed in 1995 for a 30+ year record of movement. Maximum surface velocity is 45 cm/yr on gentle slopes and 80 cm/yr in a steep reach where GCRG spills out of the cirque. The less active, downvalley third of GCRG is moving at a maximum 14 cm/yr, and lobes formed between the more and less active parts have complex movement and are advancing down-valley over adjacent lobes at a maximum of 6.5 cm/yr. New refraction seismic profiles on GCRG were used to determine the thickness of the debris mantle over ice. On the up-valley, active part of GCRG, the debris mantle is a relatively uniform c. 1 m thick. On the down-valley, less active part, the thickness of the debris mantle is much more variable, but it is generally thicker. We cannot tell, on the basis of seismic data alone, whether the frozen material beneath the debris mantle is ice or a debris-ice mixture, but the results are not inconsistent with the glacigenic model for the origin of the ice. Two long-profiles in the cirque may identify bedrock at about 20-25 m depth.

Water samples collected from rivers in the Mississippi River Basin were analyzed for selected herbicides to evaluate their discharge to the Gulf of Mexico and to identify their predominant source areas within the basin. Samples were collected from the Mississippi River at Baton Rouge, LA from 1991 to 1997 and from sites on the upper Mississippi, the Missouri, and the Ohio Rivers from 1996 to 1997. Atrazine, metolachlor, and alachlor ESA (an alachlor metabolite) were the most frequently detected herbicides in the Mississippi River at Baton Rouge, and, in general, were present in the largest concentrations. The peak annual herbicide load was in 1993 when about 640 metric tons of atrazine, 320 metric tons of cyanazine, 215 metric tons of metolachlor, 53 metric tons of simazine, and 50 metric tons of alachlor were discharged to the Gulf of Mexico. The annual load of atrazine and cyanazine was generally 1-3% of the amount annually applied in the Mississippi River drainage basin; the annual load of acetochlor, alachlor, and metolachlor was generally less than 1%. During 1996-1997 the Ohio River contributed about 50% of the discharge and 50% or more of the herbicide load to the Gulf of Mexico.