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[1] The quality of the version 2.2 (v2.2) middle atmosphere water vapor and nitrous oxide measurements from the Microwave Limb Sounder (MLS) on the Earth Observing System (EOS) Aura satellite is assessed. The impacts of the various sources of systematic error are estimated by a comprehensive set of retrieval simulations. Comparisons with correlative data sets from ground-based, balloon and satellite platforms operating in the UV/visible, infrared and microwave regions of the spectrum are performed. Precision estimates are also validated, and recommendations are given on the data usage. The v2.2 H 2 O data have been improved over v1.5 by providing higher vertical resolution in the lower stratosphere and better precision above the stratopause. The single-profile precision is $0.2-0.3 ppmv (4-9%), and the vertical resolution is $3-4 km in the stratosphere. The precision and vertical resolution become worse with increasing height above the stratopause. Over the pressure range 0.1-0.01 hPa the precision degrades from 0.4 to 1.1 ppmv (6-34%), and the vertical resolution degrades to $12-16 km. The accuracy is estimated to be 0.2-0.5 ppmv (4-11%) for the pressure range 68-0.01 hPa. The scientifically useful range of the H 2 O data is from 316 to 0.002 hPa, although only the 82-0.002 hPa pressure range is validated here. Substantial improvement has been achieved in the v2.2 N 2 O data over v1.5 by reducing a significant low bias in the stratosphere and eliminating unrealistically high biased mixing ratios in the polar regions. The single-profile precision is $13-25 ppbv (7-38%), the vertical resolution is $4-6 km and the accuracy is estimated to be 3-70 ppbv (9-25%) for the pressure range 100-4.6 hPa. The scientifically useful range of the N 2 O data is from 100 to 1 hPa. Citation: Lambert, A., et al. (2007), Validation of the Aura Microwave Limb Sounder middle atmosphere water vapor and nitrous oxide measurements,

Interannual variations of stratospheric water vapor over 1992-2003 are studied using Halogen Occultation Experiment (HALOE) satellite measurements. Interannual anomalies in water vapor with an approximate 2-yr periodicity are evident near the tropical tropopause, and these propagate vertically and latitudinally with the mean stratospheric transport circulation (in a manner analogous to the seasonal ''tape recorder''). Unusually low water vapor anomalies are observed in the lower stratosphere for 2001-03. These interannual anomalies are also observed in Arctic lower-stratospheric water vapor measurements by the Polar Ozone and Aerosol Measurement (POAM) satellite instrument during 1998-2003. Comparisons of the HALOE data with balloon measurements of lower-stratospheric water vapor at Boulder, Colorado (40ЊN), show partial agreement for seasonal and interannual changes during 1992-2002, but decadal increases observed in the balloon measurements for this period are not observed in HALOE data. Interannual changes in HALOE water vapor are well correlated with anomalies in tropical tropopause temperatures. The approximate 2-yr periodicity is attributable to tropopause temperature changes associated with the quasi-biennial oscillation and El Nin ˜o-Southern Oscillation.

Abstract. Ten data sets coveting the period 1954-2000 are analyzed to show a 1%/yr increase in stratospheric water vapor. The trend has persister for at least 45 years, hence is unl•ely the result of a single event, but rather indicative of long-term climate change. A long-term change in the transport ofwater vapor into the stratosphere is the most probable cause.

International audienceOzone profile trends over the period 2000 to 2016 from several merged satellite ozone data sets and from ground-based data by four techniques at stations of the Network for the Detection of Atmospheric Composition Change indicate significant ozone increases in the upper stratosphere, between 35 and 48 km altitude (5 and 1 hPa). Near 2 hPa (42 km), ozone has been increasing by about 1.5 % per decade in the tropics (20° S to 20° N), and by 2 to 2.5 % per decade in the 35° to 60° latitude bands of both hemispheres. At levels below 35 km (5 hPa), 2000 to 2016 ozone trends are smaller and not statistically significant. The observed trend profiles are consistent with expectations from chemistry climate model simulations. Using three to four more years of observations and updated data sets, this study confirms positive trends of upper stratospheric ozone already reported, e.g., in the WMO/UNEP Ozone Assessment 2014, or by Harris et al. (2015). The additional years, and the fact that nearly all individual data sets indicate these increases, give enhanced confidence. Nevertheless, a thorough analysis of possible drifts and differences between various data sources is still required, as is a detailed attribution of the observed increases to declining ozone depleting substances and to stratospheric cooling. Ongoing quality observations from multiple independent platforms are key for verifying that recovery of the ozone layer continues as expected

Fires in southeastern Australia produced at least 18 pyrocumulonimbus (pyroCb) between 29 December 2019 and 4 January 2020. The largest plumes from this event exhibited several previously undocumented phenomena in the stratosphere. These include (i) the generation of potential vorticity and anticyclonic circulations from absorptive aerosol heating, (ii) the formation of a vertical temperature anomaly dipole, (iii) the rapid ascent from the lowermost stratosphere (15–16 km) to altitudes above 31 km in less than 2 months, (iv) an unprecedented abundance of H2O and CO in the stratosphere, and (v) the displacement of background O3 and N2O from rapid ascent of air from the troposphere and lower stratosphere. Each of these phenomena is traced back to a 5‐day‐old stratospheric plume composed of a massive amount of aerosol and biomass burning gases from a pyroCb outbreak. Until now, there has been no documented evidence that pyroCb plumes can affect stratospheric winds.

Unusually large planetary wave activity in the 2002 Antarctic winter stratosphere weakened and warmed the polar vortex. Three minor warmings during August and early September preceded a late‐September major warming when the middle stratospheric zonal winds reversed to easterly and the polar temperature increased by an additional 25 K. Polar Ozone and Aerosol Measurement (POAM III) ozone data at high southern latitudes show unusually large variability in 2002 compared to previous POAM III years (1998–2001). Analyses of air parcel transport indicate this variability is caused by large‐scale isentropic transport. Diagnostics of transport and mixing show that during the major warming the lower stratospheric vortex remained intact, while the middle stratospheric vortex split into two pieces; one piece rapidly mixed with extravortex air, while the other returned to the pole as a much weaker and smaller vortex.

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