A magnetically recoverable, efficient and selective copper based nanocatalyst has been synthesised via covalent grafting of 2-acetylthiophene on a silica coated magnetic nanosupport followed by metallation with copper acetate. The obtained organic-inorganic hybrid nanomaterial has been characterized by electron microscopy techniques (SEM and TEM with EDS), XRD, VSM, FT-IR and AAS. The catalytic performance of the novel nano-catalyst is evaluated in the active transformation of various aromatic amines to industrially-important alkylated amines. The nanocomposites afford high turnover frequency and high selectivity for amines under aerobic conditions. Furthermore, the heterogeneous nature of the catalyst allows easy magnetic recovery and regeneration, which makes the present protocol highly beneficial to address the industrial needs and environmental concerns. † Electronic supplementary information (ESI) available. See

A novel silica nanosperes supported diazafluorene iron complex has been fabricated and found to be effective in three-component coupling reaction of terminal alkynes, dichloromethane and amines.

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Advancement in industrialization and urbanization is a good indicator of the progress of humanity. However, it has an evil side as well. This advancement is identified as being responsible for deleterious effects on the health of human beings and aquatic biodiversity. Anthropogenic activities like mining and disposal of treated/untreated waste effluents containing toxic metals have resulted in severe deterioration of water quality, rendering serious environmental problems. The basic problem is that the wastewater generated through industries is not given the necessary pretreatment and is discharged directly into water resources. The metals beyond their permissible limits cause maximum negative impacts owing to their long biological half-lives and nondegradable nature. The condition is further worsening in economically deprived countries, where this metal-contaminated wastewater is directly used in various agricultural and day-to-day practices. As a solution to this, the extraction and removal of toxic metal ions from these polluted water resources at an industrial level is of paramount importance. This chapter provides the enthusiastic efforts of the scientific community to disseminate the fundamentals and practices of green analytical methods for metal removal. These methods are based on solid-phase extraction using functionalized silica gel for the separation and preconcentration of metal ions in polluted water resources. Ease of synthesis and extensive application of these organic-inorganic hybrid materials helps to fulfil the commitment of continual environmental improvement by remediating the wastewater.

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