Built environment stocks (buildings and infrastructures) play multiple roles in our socio-economic metabolism: they serve as the backbone of modern societies and human well-being, drive the material cycles throughout the economy, entail temporal and spatial lock-ins on energy use and emissions, and represent an extensive reservoir of secondary materials. This review aims at providing a comprehensive and critical review of the state of the art, progress, and prospects of built environment stocks research which has boomed in the past decades. We include 249 publications published from 1985 to 2018, conducted a bibliometric analysis, and assessed the studies by key characteristics including typology of stocks (status of stock and end-use category), type of measurement (object and unit), spatial boundary and level of resolution, and temporal scope. We also highlighted the strengths and weaknesses of different estimation approaches. A comparability analysis of existing studies shows a clearly higher level of stocks per capita and per area in developed countries and cities, confirming the role of urbanization and industrialization in built environment stock growth. However, more spatially refined case studies (e.g., on developing cities and non-residential buildings) and standardization and improvement of methodology (e.g., with geographic information system and architectural knowledge) and data (e.g., on material intensity and lifetime) would be urgently needed to reveal more robust conclusions on the patterns, drivers, and implications of built environment stocks. Such advanced knowledge on built environment stocks could foster societal and policy agendas such as urban sustainability, circular economy, climate change, and United Nations 2030 Sustainable Development Goals.
Bottom-up synthesis of graphene nanoribbons (GNRs) is an essential step toward utilizing them in electronic and sensing applications due to their defined edge structure and high uniformity. Recently, structurally perfect GNRs with variable lengths and edge structures were created using various chemical synthesis techniques. Nonetheless, issues like GNR deposition, characterization, electronic properties, and applications are not fully explored. Here we report optimized conditions for deposition, characterization, and device fabrication of individual and thin films of ultra-long chemically synthesized GNRs. Moreover, we have demonstrated exceptional NO 2 gas sensitivity of the GNR film devices down to parts per billion (ppb) levels. The results lay the foundation for using chemically synthesized GNRs for future electronic and sensing applications.
A dynamic material flow model was developed to simulate the evolution of global aluminum stocks in geological reserve and anthropogenic reservoir from 1900 to 2010 on a country level. The contemporary global aluminum stock in use (0.6 Gt or 90 kg/capita) has reached about 10% of that in known bauxite reserves and represents an embodied energy amount that is equivalent to three-quarters of the present global annual electricity consumption. The largest proportions of in-use stock are located in the U.S. (28%), China (15%), Japan (7%), and Germany (6%) and in sectors of building and construction (40%) and transportation (27%). Industrialized countries have shown similar patterns of aluminum in-use stock growth: once the per-capita stocks have reached a threshold level of 50 kg, they kept a near linear annual growth of 5-10 kg/capita; no clear signs of saturation can yet be observed. The present aluminum in-use stocks vary widely across countries: approximately 100-600 kg/capita in industrialized countries and below 100 kg/capita in developing countries. The growing global aluminum in-use stock has significant implications on future aluminum demand and provides important recycling opportunities that will be critical for greenhouse gas emissions mitigation in the aluminum industry in the coming decades.
Reduction in strength and stiffness in rocks attributed to an increase in water content has been extensively researched on a large variety of rock types over the past decades. Due to the considerable variations of texture and lithology, the extent of water-weakening effect is highly varied among different rock types, spanning from nearly negligible in quartzite to 90 % of uniaxial compressive strength reduction in shale. Readers, however, often face difficulties in comparing the data published in different sources due to the discrepancy of experimental procedures of obtaining the water saturation state and how the raw laboratory data is interpreted. In view of this, the present paper first reviews the terminologies commonly used to quantify the amount of water stored in rocks. The second part of the paper reviews the water-weakening effects on rock strengths, particularly focusing on uniaxial compressive strength and modulus, as well as tensile strength, under quasi-static loading and dynamic loading. The correlation relationships established among various parameters, including porosity, density and fabric of rocks, and external factors such as strain rate, surface tension and dielectric constant of the saturating liquid, absorption percentage and suction pressure, are reviewed and presented toward the end of the paper.
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