Gas hydrates, a solid established by water and gas molecules, are widespread along the continental margins of the world. Their dynamics have mainly been regarded through the lens of temperature-pressure conditions. A fluctuation in one of these parameters may cause destabilization of gas hydrate-bearing sediments below the seafloor with implications in ocean acidification and eventually in global warming. Here we show throughout an example of the Black Sea, the world’s most isolated sea, evidence that extensive gas hydrate dissociation may occur in the future due to recent salinity changes of the sea water. Recent and forthcoming salt diffusion within the sediment will destabilize gas hydrates by reducing the extension and thickness of their thermodynamic stability zone in a region covering at least 2800 square kilometers which focus seepages at the observed sites. We suspect this process to occur in other world regions (e.g., Caspian Sea, Sea of Marmara).

Gashydrate in europäischen Meeresgebieten Größte Vorkommen im Schwarzen Meer und im europäischen Nordmeer 22.11.2019/Kiel. Erdgas, gespeichert in sogenannten Gashydraten, findet man weltweit an vielen Kontinentalrändern. Im Rahmen des von der Europäischen Kommission geförderten Projektes MIGRATE (Marine Gas Hydrates: An Indigenous Resource of Natural Gas for Europe) wurde nun erstmalig eine Bestandsaufnahme der Vorkommen in europäischen Meeresgebieten zusammengetragen. Teilergebnisse des vom GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel koordinierten Projektes wurden jetzt in der internationalen Fachzeitschrift Marine and Petroleum Geology veröffentlicht.

A comprehensive characterization of gas hydrate system offshore the western Black Sea was performed through an integrated analysis of geophysical data. We detected the bottom‐simulating reflector (BSR), which marks, in this area, the base of gas hydrate stability. The observed BSR depth does not fit the theoretical steady state base of gas hydrate stability zone (BGHSZ). We show that the disparity between the BSR and predicted BGHSZ is the result of a transient state of the hydrate system due to the ongoing reequilibrium since the Last Glacial Maximum. When gas hydrates are brought outside the stability zone due to changes in temperature and sea level, their dissociation generates an increase in interstitial pore pressure. This process is favorable to the recrystallization of gas hydrates and delays the upward migration of the hydrate stability zone explaining the anomalously deep BSR. The BSR depth, which is commonly used to derive geothermal gradient values by assuming steady state conditions, is used here to derive the maximum excess pore pressure at the BGHSZ. Derived excess pore pressure values of 1–2 MPa are probably the result of the low permeability of hydrate‐bearing sediments. Higher pore pressure values derived at the location of a fault system could cause hydrofracturing enabling the free gas to cross the gas hydrate stability zone and emerge at the seafloor, forming the flares observed in close vicinity to where the shallow gas hydrates were sampled.

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Abstract:In the Danube Delta, on the Sulina branch, the morphology, sediment, and bedform characteristics were investigated. Three-dimensional (3D) bathymetry, flow velocity, suspended-load concentration, and liquid and solid discharge data were acquired throughout several cross sections along the Sulina channel, in order to investigate the distribution of water and sediment discharges and their influence against the river bed. A single observation (in February 2007) was made regarding the geometry, sediment composition, and hydraulic conditions under which the dunes grew and degenerated. The investigation focuses here mostly on the geometrical parameters of these bedforms, such as height, length, as well as grain size characteristic of the sediment and water dynamics. Based on in-site measurements, different hydraulic parameters were calculated, such as bed shear stresses and Reynolds number. During the field campaign, the measured water mean velocity was from v = 0.22-1.13 m·s −1 . At the same time, the measured range of shear stresses within the dune field formation was from τ 0 = 2.86 N·m −2 (on the cutoffs) to 8.62 N·m −2 (on the main channel). It was found that the correlation between height (H) and length (L) of the Sulina branch dunes describes the formula: H = 0.093L 0.5268 . The bedforms of the Sulina channel are, in general, developed in fine sand (D 50 between 0.06 and 0.35 mm).