[1] Based on acquired geophysical, geological and geotechnical data and modeling, we suggest hydrate dissolution to cause sediment collapse and pockmark formation in the Niger delta. Very high-resolution bathymetry data acquired from the Niger delta reveal the morphology of pockmarks with different shapes and sizes going from a small ring depression surrounding an irregular floor to more typical pockmarks with uniform depression. Geophysical data, in situ piezocone measurements, piezometer measurements and sediment cores demonstrate the presence of a common internal architecture of the studied pockmarks: inner sediments rich in gas hydrates surrounded by overpressured sediments. The temperature, pressure and salinity conditions of the studied area have allowed us to exclude the process of gas-hydrate dissociation (gas hydrate turns into free gas/water mixture) as a trigger of the observed pockmarks. Based on numerical modeling, we demonstrate that gas-hydrate dissolution (gas hydrate becomes mixture of water and dissolved gas) under a local decrease of the gas concentration at the base of the gas-hydrate occurrence zone (GHOZ) can explain the excess pore pressure and fluid flow surrounding the central hydrated area and the sediment collapse at the border of the GHOZ. The different deformation (or development) stages of the detected pockmarks confirm that a local process such as the amount of gas flow through faults rather than a regional one is at the origin of those depressions. Citation: Sultan, N., et al. (2010), Hydrate dissolution as a potential mechanism for pockmark formation in the Niger delta,

We acquired coincident marine controlled source electromagnetic (CSEM), high‐resolution seismic reflection and ocean‐bottom seismometer (OBS) data over an active pockmark in the crest of the southern part of the Vestnesa Ridge, to estimate fluid composition within an underlying fluid‐migration chimney. Synthetic model studies suggest resistivity obtained from CSEM data can resolve gas or hydrate saturation greater than 5% within the chimney. Acoustic chimneys imaged by seismic reflection data beneath the pockmark and on the ridge flanks were found to be associated with high‐resistivity anomalies (+2–4 Ωm). High‐velocity anomalies (+0.3 km/s), within the gas‐hydrate stability zone (GHSZ) and low‐velocity anomalies (−0.2 km/s) underlying the GHSZ, were also observed. Joint analysis of the resistivity and velocity anomaly indicates pore saturation of up to 52% hydrate with 28% free gas, or up to 73% hydrate with 4% free gas, within the chimney beneath the pockmark assuming a nonuniform and uniform fluid distribution, respectively. Similarly, we estimate up to 30% hydrate with 4% free gas or 30% hydrate with 2% free gas within the pore space of the GHSZ outside the central chimney assuming a nonuniform and uniform fluid distribution, respectively. High levels of free‐gas saturation in the top part of the chimney are consistent with episodic gas venting from the pockmark.

[1] In recent years, it has become evident that features commonly called gas chimneys provide major routes for methane to pass through the methane-hydrate stability zone in continental margins and escape to the ocean. One of many such chimneys lying beneath pockmarks in the southeastern Vøring Plateau off Norway was investigated with a high-resolution seismic experiment employing a 2-D array of sixteen 4-component ocean bottom seismic recorders at approximately 100 m separation and a dense network of shots to define the 3-D variation of the chimney's structure and seismic properties. The tomographic model derived from P wave travel times shows that P wave velocity inside the chimney is up to 300 m/s higher than in the surrounding strata within the methanehydrate stability zone. The zone of anomalously high velocity, about 500 m wide near its base, narrowing to about 200 m near the seabed, extends to a depth of 250 m below the seafloor. The depth extent of this zone and absence of high velocity beneath the base of the methane-hydrate stability field make it more likely that it contains hydrate rather than carbonate. If a predominantly fracture-filling model is appropriate for the formation of hydrate in low-permeability sediment, the maximum hydrate concentration in the chimney is estimated to be 14%-27% by total volume, depending on how host-sediment properties are affected by hydrate formation. Doming of the strata penetrated by the chimney appears to be associated with the emplacement of hydrate, accompanying the invasion of the gas hydrate stability zone by free gas.Citation: Plaza-Faverola, A., G. K. Westbrook, S. Ker, R. J. K. Exley, A. Gailler, T. A. Minshull, and K. Broto (2010), Evidence from three-dimensional seismic tomography for a substantial accumulation of gas hydrate in a fluid-escape chimney in the Nyegga pockmark field, offshore Norway,

Gas hydrates, a solid established by water and gas molecules, are widespread along the continental margins of the world. Their dynamics have mainly been regarded through the lens of temperature-pressure conditions. A fluctuation in one of these parameters may cause destabilization of gas hydrate-bearing sediments below the seafloor with implications in ocean acidification and eventually in global warming. Here we show throughout an example of the Black Sea, the world’s most isolated sea, evidence that extensive gas hydrate dissociation may occur in the future due to recent salinity changes of the sea water. Recent and forthcoming salt diffusion within the sediment will destabilize gas hydrates by reducing the extension and thickness of their thermodynamic stability zone in a region covering at least 2800 square kilometers which focus seepages at the observed sites. We suspect this process to occur in other world regions (e.g., Caspian Sea, Sea of Marmara).

A series of pockmarks observed at the seabed matches well the perimeter of a large submarine landslide, called NG1, located on the outer shelf and continental slope of the Eastern Gulf of Guinea. NG1 extends over 200 km2, is covered by a 120-m thick sedimentary layer which tapers downslope, and has an internal structure clearly identified in 3D seismic data consisting of three adjacent units on the upper continental slope. The pockmarks above NG1 have a diameter of several tens of meters and reveal distinct origins: (1) linked to >500 m deep fluid reservoirs, (2) rooted in NG1 internal discontinuities between NG1 units, and (3) well above NG1, superficially rooted in a regional conformity (D40), which marks the lowest sea level of the Marine Isotope Stage 6. The regional stratigraphic pattern of the study area is composed of muddy sedimentary sequences separated by correlative conformities and transgressive condensed units of coarser grain size. Mud-confined coarser-grained units constitute transient gas reservoirs favoring lateral gas migration and formation of pockmarks rooted in the condensed units. The buried NG1 landslide modifies the layered structure of the sedimentary column providing (1) overall, a barrier to fluid migration, and (2) localized pathways for fluid migration. The triggering factor for the formation of pockmarks above NG1 can be the variation of hydrostatic pressure driven by relative sea-level fall during Marine Isotopic Stages 6 and 2 and consequent gas exsolution and fluid flow. We anticipate our result to be a starting point for understanding the role of gas seeps on climate change worldwide. Furthermore, gas release intensifies during lowstands with relevant implication on global warming after ice ages. Highlights ►This is the first study linking the effect of a landslide on gas migration pathways. ►Pockmark formation is reconstructed with geophysical and geotechnical data. ►The landslide occurred during a sea-level fall period. ►The timing of pockmark formation is in part controlled by 100-kyr eustatic cycles. ►Once buried, the landslide controls the spatial organization of pockmarks.