Differential scanning calorimetry (DSC) has been combined with transmission electron microscopy (TEM) to investigate the low-temperature decomposition processes taking place in an Al-5 wt pct Zn-1 wt pct Mg alloy. It was confirmed that two types of GP zones, i.e., GP(I) (solute-rich clusters) and GP(II) (vacancy-rich clusters), formed independently during decomposition of the supersaturated solid solution. The GP(I) zones form at a relatively low aging temperature and dissolve when the aging temperature is increased. The GP(II) zones are stable over a wider range of temperatures. To investigate the nature of the zones in the Al-Zn-Mg alloy, differential scanning calorimetry and transmission electron microscopy have also been carried out on binary Al-Zn alloys containing 5 wt pct and 10 wt pct Zn. In these Al-Zn alloys, GP zones formed rapidly during quenching, and they gave rise to characteristic electron diffraction patterns identical to those from GP(II) in the Al-ZnMg alloy system, implying that GP(II) zones in Al-Zn-Mg alloys are very similar to the zones formed in binary Al-Zn alloys. Thus, it is likely that GP(II) zones in Al-Zn-Mg alloys are zinc-rich clusters. In the Al-5 wt pct Zn-1 wt pct Mg alloy, both GP(I) and GP(II) were found to transform to Ј and/ or particles during heating in the differential scanning calorimeter. The Ј was also observed to form after prolonged isothermal aging of the Al-Zn-Mg alloy at 75 ЊC or after short aging times at 125 ЊC.
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